Facile Solvothermal Synthesis of Black Phosphorus Nanosheets from Red Phosphorus for Efficient Photocatalytic Hydrogen Evolution

被引：51
作者：
Zhu, Shuting [1 ]
Liang, Qingshuang [1 ]
Xu, Yating [1 ]
Fu, Hanping [1 ]
Xiao, Xiufeng [1 ]
机构：
[1] Fujian Normal Univ, Coll Chem, Fujian Prov Key Lab Adv Materials Oriented Chem E, Mat Sci, Fuzhou, Fujian, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 2020卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Solvothermal synthesis; Black phosphorus nanosheets; Phase transitions; Photocatalysis; Hydrogen evolution; PERFORMANCE; GRAPHENE; HYBRID; GROWTH; LAYER; ANODE;
D O I：
10.1002/ejic.202000048
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, we report a facial one-step solvothermal synthesis of BP nanosheets from red phosphorus based on common laboratory conditions at low temperature. This bottom-up approach for the direct preparation of BP nanosheets can be up to 2.1 g for one batch and the efficiency of the phase transition is up to 100 %. The as-prepared BP nanosheets show highly efficient photocatalytic performance. Its efficiency of photocatalytic hydrogen evolution from water is 40.6 times higher than that of red phosphorus precursor and is close to the well-known C3N4 nanosheets. Therefore, we firmly believe that this facile, scalable, and low-cost approach opens a new route to prepare black phosphorus nanosheets and will take a step to the rapid development and applications of this unique 2D material.
引用
收藏
页码：773 / 779
页数：7
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