catena-Poly[[aquazinc(II)]-μ-2-carboxylato-phenoxyacetato]

被引:13
作者
Yang, Y
Meng, FY
Zeng, MH [1 ]
Ng, SW
机构
[1] Guangxi Normal Univ, Dept Chem, Guilin 541000, Guangxi, Peoples R China
[2] Yulin Normal Coll, Dept Chem, Yulin 537000, Guangxi, Peoples R China
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词
D O I
10.1107/S1600536805012729
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The - OCH2CO2 arm of the ligand in the title compound, [Zn(C9H6O5)(H2O)](n), uses the single- bond carboxyl O atom, as well as the ether O atom, to chelate to the Zn atom; the other - CO2 arm bridges adjacent Zn atoms into a helical chain that propagates by means of a 2(1) screw axis. The - OCH2CO2 arm features distinct single- and double-bond C - O distances; in the other - CO2 arm, the C - O distances are interpreted in terms of a delocalized carboxyl group. The coordination about zinc is completed by a water molecule, resulting a distorted ZnO5 square-pyramidal arrangement in which the apical position is occupied by water.
引用
收藏
页码:M986 / M988
页数:3
相关论文
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