Kinetic Parameters of Binary Iron/Oxidant Pyrolants

被引：21

作者：

Shamsipur, Mojtaba ^{[1
]}

Pourmortazavi, Seied Mahdi ^{[1
]}

Fathollahi, Manochehr ^{[2
]}

机构：

[1] Razi Univ, Dept Chem, Kermanshah 67146, Iran

[2] Malek Ashtar Univ, Tehran, Iran

来源：

JOURNAL OF ENERGETIC MATERIALS | 2012年 / 30卷 / 02期

关键词：

ignition temperature; iron powder; kinetic parameters; pyrotechnic; thermal reactivity; PYROTECHNIC MIXTURES; IGNITION; CHLORATE;

D O I：

10.1080/07370652.2010.542798

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The thermal properties of pyrotechnic mixtures containing iron powder as fuel and KNO3, KClO3, and KClO4 as oxidants are reported. The thermogravimetry differential thermal analysis results for pure components and corresponding pyrotechnic mixtures revealed that the melting point, decomposition temperature, and rate of oxygen releasing of the oxidants have dominant effects on ignition reaction of the pyrotechnic mixtures. The apparent activation energy and activation parameters for the combustion processes were evaluated from the differential scanning calorimetry experiments. Based on the ignition temperatures obtained and the resulting kinetic data, the thermal reactivity of the pyrotechnic mixtures was found to decrease as in the order Fe+KClO3 > Fe+KNO3 > Fe+KClO4.

引用

页码：97 / 106

页数：10

共 17 条

[1] THE KINETIC AND MECHANISTIC EVALUATION OF NMR-SPECTRA [J].