Imaging Isolated Gold Atom Catalytic Sites in Zeolite NaY

被引：179
作者：
Lu, Jing [1 ]
Aydin, Ceren [1 ]
Browning, Nigel D. [1 ]
Gates, Bruce C. [1 ]
机构：
[1] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 24期
关键词：
electron microscopy; gold; interfaces; zeolites; TRANSMISSION ELECTRON-MICROSCOPY; LOW-TEMPERATURE OXIDATION; SUPPORTED GOLD; CO OXIDATION; CHEMOSELECTIVE HYDROGENATION; CARBON-MONOXIDE; COMPLEXES; NANOPARTICLES; RESOLUTION; HYDROAMINATION;
D O I：
10.1002/anie.201107391
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
As good as atomic gold: Aberration-corrected scanning transmission electron microscopy images of zeolite NaY-supported mononuclear gold complexes, obtained with atomic resolution of the gold atoms, showed the locations of the gold complexes in the zeolite framework (see picture) and identified them as the catalytically active species for CO oxidation at 298K and 1bar. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5842 / 5846
页数：5
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