A Novel Electro-Organic Synthesis of Aniline-Based Copolymers at Platinum Electrodes

被引:12
|
作者
Saraswat, Apoorv [1 ]
Sharma, Laxmi Kant [1 ]
Srivastava, Manish K. [1 ]
Siddiqui, I. R. [1 ]
Singh, R. K. P. [1 ]
机构
[1] Univ Allahabad, Dept Chem, Electrochem Lab Green Synth, Allahabad 211002, Uttar Pradesh, India
关键词
copolymerization; conducting polymers; electrochemistry; controlled potential electrolysis; supporting electrolyte; ecofriendly; POLYANILINE; 2-AMINO-5-SUBSTITUTED-1,3,4-OXADIAZOLES; POLYMERIZATION; CONDUCTIVITY; POLYPYRROLE; PH;
D O I
10.1002/app.34621
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel, efficient, and ecocompatible electro copolymerization of anilines at platinum electrode using acetonitrile as non-aqueous solvent and lithiumperchlorate as supporting electrolyte was carried and described here. The progress and mechanistic study of copolymerization was done using cyclic voltammetry. The reaction proceeded smoothly and quantitatively at ambient temperature. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 1479-1485, 2012
引用
收藏
页码:1479 / 1485
页数:7
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