FeSO4•7H2O-catalyzed oxidative amidation of methylarenes

被引：17
|
作者：
Karimi, Meghdad [1 ]
Saberi, Dariush [2 ]
Azizi, Kobra [1 ]
Ghonchepour, Ehsan [1 ]
Heydari, Akbar [1 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Tehran, Iran
[2] Persian Gulf Univ, Coll Agr & Nat Resources, Dept Fisheries & Aquaculture, Bushehr 75169, Iran
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 21期
关键词：
Catalyst; Oxidation; Amidation; Methylarenes; tert-Butyl hydroperoxide; AMIDE BOND FORMATION; CARBOXYLIC-ACIDS; BENZYL ALCOHOLS; MILD AMIDATION; ALDEHYDES; AMINES; HYDROCHLORIDE; TRANSAMIDATION; SALTS; AMINATION;
D O I：
10.1016/j.tetlet.2015.03.114
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method has been described employing FeSO4 center dot 7H(2)O as a catalyst for the synthesis of amides from methylarenes and amines (hydrochloride salts) with tert-butyl hydroperoxide as an external oxidant. Primary, secondary, and tertiary amides were synthesized in moderate to good yields. A variety of amines and methylarenes were used to investigate the scope of this process. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2674 / 2677
页数：4
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