Enhanced yellow afterglow in Ca2SnO4:Dy3+ by co-doping Na+/K+

被引:12
作者
Chen, Yue [1 ]
Zou, Jun [1 ]
Shi, Mingming [1 ]
Yang, Bobo [1 ]
机构
[1] Shanghai Inst Technol, Sch Mat Sci & Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China
基金
中国国家自然科学基金;
关键词
LUMINESCENCE PROPERTIES; PHOSPHOR; ENERGY; PHOTOLUMINESCENCE; EMISSION; BEHAVIOR; DESIGN; GREEN; EU2+;
D O I
10.1039/d0ra00656d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new yellow long afterglow luminescent material Ca2SnO4:Dy3+ was prepared by the solid state method at 1350 degrees C. The yellow LLP (long-lasting phosphorescent) material Ca2SnO4:Dy3+ was prepared by co-doping alkaline ions (K+ and Na+) and investigated using an X-ray diffractometer (XRD), photoluminescence spectrometer, afterglow meter and thermoluminescence spectrometer. The excitation and emission spectra showed an excitation peak at 350 nm and an emission peak at 573 nm. The optimized Dy3+ dopant concentration was found to be 1 mol%. For the improvement in the photoluminescence performance, we can co-dope it with alkaline ions (K+ and Na+), with the optimal concentration of the alkaline ions being 1 mol%. On the basis of the experimental results, we constructed a probable model for explaining the mechanism of LAG in detail.
引用
收藏
页码:13076 / 13082
页数:7
相关论文
共 33 条
[1]  
[Anonymous], J ALLOYS COMPD
[2]  
[Anonymous], CHEMINFORM
[3]   Reevaluation of dietary methionine requirement by plasma methionine and ammonia concentrations in surgically modified rainbow trout, Oncorhynchus mykiss [J].
Bae, J. -Y. ;
Ok, I. -H. ;
Lee, S. ;
Hung, S. S. O. ;
Min, T. S. ;
Bai, S. C. .
JOURNAL OF APPLIED ICHTHYOLOGY, 2011, 27 (03) :887-891
[4]   Charge compensated derived enhanced red emission from Sr3(VO4)2:Eu3+ nanophosphors for white light emitting diodes and flat panel displays [J].
Bedyal, A. K. ;
Kumar, Vinay ;
Swart, H. C. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 709 :362-372
[5]   Near-infrared quantum cutting in Ce3+, Yb3+ co-doped YBO3 phosphors by cooperative energy transfer [J].
Chen, JinDeng ;
Guo, Hai ;
Li, ZhengQuan ;
Zhang, Hao ;
Zhuang, YiXi .
OPTICAL MATERIALS, 2010, 32 (09) :998-1001
[6]   MODELING OF LUMINESCENCE QUENCHING-BASED SENSORS - COMPARISON OF MULTISITE AND NONLINEAR GAS SOLUBILITY MODELS [J].
DEMAS, JN ;
DEGRAFF, BA ;
XU, WY .
ANALYTICAL CHEMISTRY, 1995, 67 (08) :1377-1380
[7]   Energy of the first 4f7→4f65d transition of Eu2+ in inorganic compounds [J].
Dorenbos, P .
JOURNAL OF LUMINESCENCE, 2003, 104 (04) :239-260
[8]   Synthesis and characterization of Ca2Sn1-xCexO4 with blue luminescence originating from Ce4+ charge transfer transition [J].
Fu Shi-Liu ;
Yin Tao ;
Chai Fei .
CHINESE PHYSICS, 2007, 16 (10) :3129-3133
[9]   Structure and luminescence properties of a novel yellow super long-lasting phosphate phosphor Ca6BaP4O17:Eu2+,Ho3+ [J].
Guo, Haijie ;
Chen, Wenbo ;
Zeng, Wei ;
Li, Gen ;
Wang, Yuhua ;
Li, Yanyan ;
Li, Yang ;
Ding, Xin .
JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (22) :5844-5850
[10]   Syntheses, Crystal Structures and Solid-State Properties of the Lanthanoid-Containing Nanoclusters [(Ln2PW10O38)4(W3O8)(OH)4(H2O)2]26- [J].
Gupta, Rakesh ;
Saini, Mukesh Kumar ;
Hussain, Firasat .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (35) :6031-6038