Nonlinear flux-force relations and equipartition theorems for the state of minimum entropy production

被引：8

作者：

Johannessen, E ^{[1
]}

Kjelstrup, S ^{[1
]}

机构：

[1] Norwegian Univ Sci & Technol, Dept Chem, N-7491 Trondheim, Norway

来源：

JOURNAL OF NON-EQUILIBRIUM THERMODYNAMICS | 2005年 / 30卷 / 02期

关键词：

D O I：

10.1515/JNETDY.2005.009

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

We explain that the path of minimum entropy production in a system with nonlinear flux-force relations, which do not depend explicitly on the state variables of the system, can be characterised by equipartition of driving forces and equipartition of entropy production. The explanation is based on an optimal control theory formulation of the optimisation problem. The finding helps explaining recent numerical observations on the second law optimal state of chemical reactions.

引用

页码：129 / 136

页数：8

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