Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling

被引：77
|
作者：
Cavalcanti, Livia N. [1 ]
Molander, Gary A. [2 ]
机构：
[1] Univ Fed Rio Grande do Norte, Inst Quim, Natal, RN, Brazil
[2] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
来源：
TOPICS IN CURRENT CHEMISTRY | 2016年 / 374卷 / 04期
关键词：
Photoredox catalysis; Cross-coupling; Alkyltrifluoroborates; Alkylsilicates; SINGLE-ELECTRON TRANSMETALATION; DECARBOXYLATIVE ARYLATION; ALKENYL HALIDES; ARYL; LIGHT; DERIVATIVES; CHLORIDES; RADICALS; SILICATES; OXIDATION;
D O I：
10.1007/s41061-016-0037-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The traditional transition metal-catalyzed cross-coupling reaction, although well suited for C(sp2)-C(sp2) cross-coupling, has proven less amenable toward coupling of C(sp3)-hybridized centers, particularly using functional group tolerant reagents and reaction conditions. The development of photoredox/Ni dual catalytic methods for cross-coupling has opened new vistas for the construction of carbon-carbon bonds at C(sp3)-hybridized centers. In this chapter, a general outline of the features of such processes is detailed.
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页数：23
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