Needle-Leaf-Like Cu2Mo6S8 Films for Highly Efficient Visible-Light Photocatalysis

被引:6
作者
Hong, Xiaodan [1 ]
Liu, Qun [1 ]
Iocozzi, James [2 ]
Gong, Cheng [3 ]
Kong, Lingqing [1 ]
Liu, Xiangyang [1 ]
Ye, Meidan [1 ]
Lin, Zhiqun [2 ]
机构
[1] Xiamen Univ, Coll Phys Sci & Technol, Coll Mat,Res Inst Biomimet & Soft Matter, Dept Phys,Fujian Prov Key Lab Soft Funct Mat Res, Xiamen 361005, Peoples R China
[2] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
[3] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
基金
中国国家自然科学基金;
关键词
copper molybdenum sulfide; needle-leaf-like structures; ternary sulfide; visible-light photocatalysis; TIO2 NANOTUBE ARRAYS; HYDROGEN-PRODUCTION; CDS; WATER; HETEROJUNCTIONS; NANOSHEETS; SULFIDE; MOS2;
D O I
10.1002/ppsc.201700302
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ternary sulfide Cu2Mo6S8 films with needle-leaf-like structures are grown on copper plates via a facile two-step route. The needle-leaf-like Cu2Mo6S8 structures are directly converted from pregrown Cu(OH)(2) nanowires on copper plates via a hydrothermal process. Interestingly, under visible light the hierarchically structured Cu2Mo6S8 films exhibit significantly improved photocatalytic performance in the degradation of methylene blue dye when compared to Cu(OH)(2) nanowires. This result is attributed to the larger surface area from the dendritic Cu2Mo6S8 structures and the inherently faster charge transport rate of Cu2Mo6S8 as compared to Cu(OH)(2).
引用
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页数:7
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共 28 条
[1]   Self-templated synthesis of nanoporous CdS nanostructures for highly efficient photocatalytic hydrogen production under visible [J].
Bao, Ningzhong ;
Shen, Liming ;
Takata, Tsuyoshi ;
Domen, Kazunari .
CHEMISTRY OF MATERIALS, 2008, 20 (01) :110-117
[2]   Novel PbS quantum dots sensitized flower-like BiOBr with enhanced photocatalytic properties under visible light [J].
Cui, Wenquan ;
An, Weijia ;
Liu, Li ;
Hu, Jinshan ;
Liang, Yinghua .
MATERIALS LETTERS, 2014, 132 :251-254
[3]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[4]   Photocatalytic degradation of dodecyl-benzenesulfonate over TiO2-Cu2O under visible irradiation [J].
Han, Chenghui ;
Li, Zhiyu ;
Shen, Jianyi .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 168 (01) :215-219
[5]   Template-free synthesis of ternary sulfides submicrospheres as visible light photocatalysts by ultrasonic spray pyrolysis [J].
Huang, Jianhui ;
Cheuk, Wahkit ;
Wu, Yifan ;
Lee, Frank S. C. ;
Ho, Wingkei .
CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (09) :1825-1827
[6]   Optimization of CdS@MoS2 core-shell nanorod arrays for an enhanced photo-response for photo-assisted electrochemical water splitting under solar light illumination [J].
Ji, Jing ;
Sun, Baoliang ;
Shan, Fei ;
Li, Qian ;
Huang, Fucheng ;
Song, Ye ;
Wang, Feng .
RSC ADVANCES, 2016, 6 (102) :100115-100121
[7]   In-situ synthesis of Au-CdS plasmonic photocatalyst by continuous spray pyrolysis and its visible light photocatalysis [J].
Kumar, Neetesh ;
Komarala, Vamsi K. ;
Dutta, Viresh .
CHEMICAL ENGINEERING JOURNAL, 2014, 236 :66-74
[8]   Cu2Mo6S8 chevrel phase, a promising cathode material for new rechargeable Mg batteries:: A mechanically induced chemical reaction [J].
Levi, E ;
Gofer, Y ;
Vestfreed, Y ;
Lancry, E ;
Aurbach, D .
CHEMISTRY OF MATERIALS, 2002, 14 (06) :2767-2773
[9]   Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets [J].
Li, Qin ;
Guo, Beidou ;
Yu, Jiaguo ;
Ran, Jingrun ;
Zhang, Baohong ;
Yan, Huijuan ;
Gong, Jian Ru .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (28) :10878-10884
[10]   Creation of Cu2O@TiO2 Composite Photocatalysts with p-n Heterojunctions Formed on Exposed Cu2O Facets, Their Energy Band Alignment Study, and Their Enhanced Photocatalytic Activity under Illumination with Visible Light [J].
Liu, Lingmei ;
Yang, Weiyi ;
Sun, Wuzhu ;
Li, Qi ;
Shang, Jian Ku .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (03) :1465-1476