Synthesis of 1,3-Butadiene from 1-Butanol on a Porous Ceramic [Fe,Cr]/γ-Al2O3(K,Ce)/α-Al2O3Catalytic Converter

被引：3

作者：

Fedotov, A. S. ^{[1
]}

Uvarov, V. I. ^{[2
]}

Tsodikov, M. V. ^{[1
]}

Moiseev, I. I. ^{[1
]}

Paul, S. ^{[3
]}

Heyte, S. ^{[3
]}

Simon, P. ^{[3
]}

Marinova, M. ^{[4
]}

Dumeignil, F. ^{[3
]}

机构：

[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia

[2] Russian Acad Sci, Merzhanov Inst Struct Macrokinet & Mat Sci, Chernogolovka 142432, Moscow Oblast, Russia

[3] Univ Artois, Univ Lille, Cent Lille,ENSCL, UCCS,Unite Catalyse & Chim Solide,CNRS,UMR 8181, F-59000 Lille, France

[4] Univ Lille 1, CNRS, FR2638, Inst Chevreul, Bat C6, F-59655 Villeneuve Dascq, France

来源：

KINETICS AND CATALYSIS | 2020年 / 61卷 / 03期

关键词：

heterogeneous catalysis; porous ceramic catalytic converter; self-propagating high-temperature synthesis; catalytic membrane reactor; dehydration of biobutanol; dehydrogenation of butenes; monomer synthesis; 1,3-butadiene synthesis; release of ultrapure hydrogen; BUTADIENE PRODUCTION; DEHYDRATION; ETHANOL; DRY; CATALYSTS; HYDROGEN; METHANE; REACTOR; SYNGAS;

D O I：

10.1134/S002315842003009X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

-A two-stage method was developed for the synthesis of 1,3-butadiene by dehydration of 1-butanol to a mixture of butenes on gamma-Al(2)O(3)granules prepared by self-propagating high-temperature synthesis (SHS) followed by dehydrogenation of the butene fraction to 1,3-butadiene using a porous ceramic catalytic SHS converter [Fe,Cr]/gamma-Al2O3(K,Ce)/alpha-Al2O3. The dehydration of 1-butanol to the butene mixture proceeded almost completely at similar to 100% selectivity on gamma-Al(2)O(3)granules obtained by SHS at 300 degrees C, which is 50 degrees lower than on industrial gamma-alumina granules. The use of an original hybrid catalytic membrane reactor (HCMR) with selective removal of hydrogen from the reaction zone led to a similar to 1.3-fold increase in the yield of 1,3-butadiene at ultrapure hydrogen extraction of up to 16 mol % of the total amount of the hydrogen product. The catalytic activity of the system did not decrease after 20 h of experiment, in contrast to its activity in the industrial process, where catalyst regeneration is performed every 8-15 min.

引用

页码：390 / 404

页数：15

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