Anionic Porous Zn-Metalated Porphyrin Metal-Organic Framework with PtS Topology for Gas-Phase Photocatalytic CO2 Reduction

被引：37
作者：
Qin, Jian-Hua [1 ]
Xiao, Zhi [1 ]
Xu, Peng [2 ]
Li, Zhi-Hua [1 ]
Lu, Xiaoyan [1 ]
Yang, Xiao-Gang [1 ]
Lu, Weiwei [2 ]
Ma, Lu-Fang [1 ]
Li, Dong-Sheng
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471934, Peoples R China
[2] Henan Univ Sci & Technol Luoyang, Sch Chem Engn & Pharmaceut, Luoyang 471003, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 34期
基金：
中国国家自然科学基金;
关键词：
CONVERSION; EFFICIENT; PHOTOREDUCTION; CAPTURE; COMPLEX;
D O I：
10.1021/acs.inorgchem.2c01517
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Presented here are the synthesis and gas-phase photocatalytic CO2 reduction of an anionic porous Zn-metalated porphyrin metal-organic framework (MOF) induced by an ionic liquid. The desired CO2 affinity and deep conduction band position of the MOF catalyst provide strong kinetic and thermodynamic advantages for photocatalytic CO2 to CH4 conversion with high selectivity (similar to 70%) in H2O vapor.
引用
收藏
页码：13234 / 13238
页数：5
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