Structural Effects on the Physico-Chemical and Catalytic Properties of Acidic Ionic Liquids: An Overview

被引：75
作者：
Chiappe, Cinzia [1 ]
Rajamani, Sunita [1 ]
机构：
[1] Univ Pisa, Dept Chem & Ind Chem, Via Bonanno 33, I-56126 Pisa, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 28期
关键词：
Ionic liquids; Acidic ionic liquids; Lewis acids; Bronsted acids; Green chemistry; FRIEDEL-CRAFTS SULFONYLATION; DIELS-ALDER REACTION; ROOM-TEMPERATURE; OXIDATIVE DESULFURIZATION; AROMATIC-COMPOUNDS; DUAL SOLVENT; ETHYLAMMONIUM NITRATE; ORGANIC-REACTIONS; LEWIS ACIDITY; DIESEL FUEL;
D O I：
10.1002/ejoc.201100432
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acidic ionic liquids (ILs) are key systems in synthesis and their performances depend greatly on their cation and anion structure and their liquid-state organization. This microreview reports several examples of Bronsted and/or Lewis acidic ILs that have been selected to highlight the main peculiarities of these systems potentially fundamental for rational design and development of new ionic media and catalysts. Fundamental physico-chemical properties, optimization of which through tailoring of molecular structures could favor more efficient and sustainable applications, are discussed.
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收藏
页码：5517 / 5539
页数：23
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