fac-tricarbonylchlorobis(pyridine-N)rhenium and fac-tricarbonylchlorobis(4,4′-bipyridine-N)rhenium

被引：26

作者：

Bélanger, S ^{[1
]}

Hupp, JT ^{[1
]}

Stern, CL ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198006398

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural analyses for the title compounds, (OC-6-32)-tricarbonylchlorobis(pyridine-N)rhenium(I), [ReCl(C5H5N)(2)(CO)(3)], and (OC-6-32)-tricarbonylchlorobis-(4,4'-bipyridine-N)rhenium(I), [ReCl(C10H8N2)(2)(CO)(3)], show that both complexes have the expected fac-octahedral geometry. The bipyridine complex has local C-2 symmetry, with the rotation axis bisecting the N-Re-N' and OC-Re-CO angles. In contrast with closely related tetrameric assemblies which crystallize as porous channel-containing structures, the title compounds form dense crystals which are packed in a herring-bone fashion.

引用

页码：1596 / 1600

页数：5

共 22 条

[1]

BELANGER S, 1998, UNPUB J AM CHEM SOC

[2] MONONUCLEAR AND BINUCLEAR PALLADIUM(II) RHENIUM(I) COMPLEXES CONTAINING A STERICALLY HINDERED TRINUCLEATING LIGAND - 2,3,8,9,14,15-HEXAMETHYL-5,6,11,12,17,18-HEXAAZATRINAPHTHALENE (HHTN) [J].