The catalytic activity of a cyclometalated ruthenium(III) complex for aerobic oxidative dehydrogenation of benzylamines

被引：29

作者：

Aiki, Shota ^{[1
]}

Taketoshi, Ayako ^{[1
]}

Kuwabara, Junpei ^{[1
]}

Koizumi, Take-aki ^{[2
]}

Kanbara, Takaki ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Tsukuba, Ibaraki 3058573, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 06期

关键词：

Cyclometalated compounds; Ruthenium(III); Dehydrogenation; Amine; MOLECULAR-OXYGEN; AMINES; NITRILES; HYDROXIDE; ALCOHOLS; LIGANDS;

D O I：

10.1016/j.jorganchem.2010.10.063

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium(III) complex bearing benzo[h] quinoline as a cyclometalated ligand was synthesized and characterized by ESI-MS, elemental analysis, cyclic voltammetry and crystallography. The complex serves as an efficient catalyst for the aerobic oxidative dehydrogenation of benzylamines to the corresponding benzonitriles under mild conditions. (C) 2010 Elsevier B.V. All rights reserved.

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页码：1301 / 1304

页数：4

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