Host-Guest Complexation of a Pyrogallol[4]arene Derivative at the Air-Water Interface

被引：3
|
作者：
Waidely, Eric [1 ]
Pumilia, Cyrus [1 ]
Malagon, Andres [2 ]
Vargas, Edgar F. [2 ]
Li, Shanghao [1 ]
Leblanc, Roger M. [1 ]
机构：
[1] Univ Miami, Dept Chem, Cox Sci Ctr, Coral Gables, FL 33146 USA
[2] Univ Los Andes, Dept Quim, Lab Termondinam Soluc, Bogota, Colombia
来源：
LANGMUIR | 2015年 / 31卷 / 04期
基金：
美国国家科学基金会;
关键词：
LANGMUIR-BLODGETT-FILMS; MOLECULAR RECOGNITION; METAL-BINDING; CALIXARENE; MONOLAYERS; CHEMISTRY; DNA; NANOPARTICLES; CAPSULES; CADMIUM;
D O I：
10.1021/la504841u
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The host-guest properties of acetylated aryl pyrogallol[4]arene (AcPy) were studied as a Langmuir monolayer at the air-water interface. The self-assembled Langmuir monolayer properties and interactions with monovalent and divalent metal cations were investigated using surface pressure- and surface potential-area isotherms, compression-decompression cycles, stability, and infrared reflection-absorption spectroscopy (IRRAS). A favorable interaction is observed for complexation between acetylated aryl pyrogallol[4]arene with divalent calcium and cadmium cations, while no interaction is observed for monovalent sodium and potassium cations. Spectroscopic techniques allow for discrimination between cadmium and calcium complexation.
引用
收藏
页码：1368 / 1375
页数：8
相关论文
共 50 条
  • [21] HOST-GUEST COMPLEXATION - A NEW CHAPTER
    CRAM, DJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 182 (AUG): : 6 - ORGN
  • [22] A cationic water-soluble pillar[5]arene: synthesis and host-guest complexation with long linear acids
    Wu, Gui-yuan
    Shi, Bing-bing
    Lin, Qi
    Li, Hui
    Zhang, You-ming
    Yao, Hong
    Wei, Tai-bao
    RSC ADVANCES, 2015, 5 (07) : 4958 - 4963
  • [23] HOST-GUEST COMPLEXATION OF NEUTRAL SPECIES
    STEWART, KD
    CRAM, DJ
    GOLDBERG, I
    TRUEBLOOD, KN
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 160 - ORGN
  • [24] Mechanism of host-guest complexation by cucurbituril
    Márquez, C
    Hudgins, RR
    Nau, WM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (18) : 5806 - 5816
  • [25] SOLVENT EFFECTS ON HOST-GUEST COMPLEXATION
    SPENCER, JN
    MIHALICK, JE
    PAUL, IM
    NICHOLSON, WJ
    NICHOLSON, TJ
    KE, X
    HE, Q
    CARTER, FJ
    DANIELS, SE
    FENTON, LJ
    EALY, JL
    PUPPALA, S
    YODER, CH
    JOURNAL OF SOLUTION CHEMISTRY, 1994, 23 (06) : 711 - 720
  • [26] STRUCTURAL STUDIES OF HOST-GUEST COMPLEXATION
    GOLDBERG, I
    ACTA CRYSTALLOGRAPHICA SECTION A, 1975, 31 : S166 - S166
  • [27] Investigation of the host-guest complexation between 4-sulfocalix[4]arene and nedaplatin for potential use in drug delivery
    Fahmy, Sherif Ashraf
    Ponte, Fortuna
    Abd El-Rahman, Mohamed K.
    Russo, Nino
    Sicilia, Emilia
    Shoeib, Tamer
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2018, 193 : 528 - 536
  • [28] Proton Transfer in Host-Guest Complexation between a Difunctional Pillar[5]arene and Alkyldiamines
    Yu, Guocan
    Hua, Bin
    Han, Chengyou
    ORGANIC LETTERS, 2014, 16 (09) : 2486 - 2489
  • [29] Host-guest cocrystals derived from pyrogallol[4]arenes and ionic liquids
    Fowler, Drew A.
    Baker, Gary A.
    Atwood, Jerry L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [30] Effect of Lower-Rim Alkylation of p-Sulfonatocalix[4]arene on the Thermodynamics of Host-Guest Complexation
    Cui, Jie
    Uzunova, Vanya D.
    Guo, Dong-Sheng
    Wang, Kui
    Nau, Werner M.
    Liu, Yu
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (09) : 1704 - 1710
12345