A ferromagnetically coupled diiron(III) complex with a m-phenylenediamine-based ligand

被引：4

作者：

Biswas, Biplab ^{[1
]}

Salunke-Gawali, Sunita ^{[1
]}

Weyhermueller, Thomas ^{[1
]}

Bachler, Vinzenz ^{[1
]}

Bill, Eckhard ^{[1
]}

Chaudhuri, Phalguni ^{[1
]}

机构：

[1] Max Planck Inst Bioinorgan Chem, D-45470 Mulheim, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 15期

关键词：

iron; diferric complexes; Schiff bases; ferromagnetism; spin polarization;

D O I：

10.1002/ejic.200800255

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Schiff base ligand H2L, N,N'-bis(3,5-di-tert-butylsalicylidene)-1,3-diaminobenzene yields a diferric complex, [L2Fe2III(NO3)(2)] (1), in which the d(5) high-spin iron(III) centers are ferromagnetically coupled through the spin polarization mechanism. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：2391 / 2395

页数：5

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