A ferromagnetically coupled diiron(III) complex with a m-phenylenediamine-based ligand

被引：4

作者：

Biswas, Biplab ^{[1
]}

Salunke-Gawali, Sunita ^{[1
]}

Weyhermueller, Thomas ^{[1
]}

Bachler, Vinzenz ^{[1
]}

Bill, Eckhard ^{[1
]}

Chaudhuri, Phalguni ^{[1
]}

机构：

[1] Max Planck Inst Bioinorgan Chem, D-45470 Mulheim, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 15期

关键词：

iron; diferric complexes; Schiff bases; ferromagnetism; spin polarization;

D O I：

10.1002/ejic.200800255

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Schiff base ligand H2L, N,N'-bis(3,5-di-tert-butylsalicylidene)-1,3-diaminobenzene yields a diferric complex, [L2Fe2III(NO3)(2)] (1), in which the d(5) high-spin iron(III) centers are ferromagnetically coupled through the spin polarization mechanism. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：2391 / 2395

页数：5

共 38 条

[1] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[2] Homo- and hetero-polymetallic exchange coupled metal-oximates [J].

Chaudhuri, P .

COORDINATION CHEMISTRY REVIEWS, 2003, 243 (1-2) :143-190

[3]

Cotton F. A., 1999, Advanced Inorganic Chemistry

[4] Bonding coordination requirements induce antiferromagnetic coupling between m-phenylene bridged o-iminosemiquinonato diradicals [J].

Dei, A ;

Gatteschi, D ;

Sangregorio, C ;

Sorace, L ;

Vaz, MGF .

INORGANIC CHEMISTRY, 2003, 42 (05) :1701-1706

[5]

Fernández I, 2001, ANGEW CHEM INT EDIT, V40, P3039, DOI 10.1002/1521-3773(20010817)40:16<3039::AID-ANIE3039>3.0.CO

[6]

2-P

[7]

FIGATO PA, 2004, COORDIN CHEM REV, V248, P1717

[8]

Frisch M.J., 2004, Gaussian 03

[9]

Revision C.02

[10] Targeted ferromagnetic coupling in a trinuclear copper(II) complex:: Analysis of the St-3/2 spin ground state [J].

Glaser, T ;

Heidemeier, M ;

Grimme, S ;

Bill, E .

INORGANIC CHEMISTRY, 2004, 43 (17) :5192-5194

← 1 2 3 4 →