Slow magnetic relaxation in a novel heptanuclear Dy7 cluster with five edge-sharing Dy3 triangles

被引：20
作者：
Guo, Fu-Sheng [1 ]
Guo, Peng-Hu [1 ]
Meng, Zhao-Sha [1 ]
Tong, Ming-Liang [1 ,2 ]
机构：
[1] Sun Yat Sen Univ, Key Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Minist Educ,Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
POLYHEDRON | 2011年 / 30卷 / 18期
关键词：
Lanthanide complex; Cluster; Edge-sharing; Single molecule magnet; SINGLE-MOLECULE-MAGNET; DYSPROSIUM TRIANGLES; AGGREGATE;
D O I：
10.1016/j.poly.2011.02.038
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A unique Dy-7 cluster with five edge-sharing Dy-3 triangles has been synthesized by incorporating the polydentate oxime ligand, 3-methyloxysalicylaldoxime, in two different binding modes in its mono- and di-deprotonated state. Both static (dc) and dynamic (ac) magnetic properties of 1 have been studied, possible single-molecule magnet behavior is observed, expanding upon the recent reports of the pure 4f type SMM. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3079 / 3082
页数：4
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