Synthesis, crystal structure, thermal stability, and magnetic properties of a paramagnetic Co(II) [Co2(p-bdc)4(dfdp)4)]n derived from 1,4-benzenedicarboxylic acid and 4,4′-(2,5-difluoro-1,4-phenylene)dipyridine

被引：0
|
作者：
Yang, Xiaolin [1 ]
Yang, Yi [1 ]
Tu, Yuyu [2 ]
Lin, Lan [3 ]
Wang, Fei [1 ]
Yin, Rui [2 ]
Jiang, Tianyu [1 ]
Chen, Ziying [1 ]
Ju, Yichun [3 ]
机构：
[1] Changzhou Vocat Inst Engn, Changzhou 213164, Jiangsu, Peoples R China
[2] Nanjing Med Univ, Sch Med Imaging, Nanjing 211166, Peoples R China
[3] Nanjing Med Univ, Sch Pharm, Key Lab Cardiovasc & Cerebrovasc Med, Nanjing 211166, Peoples R China
来源：
MONATSHEFTE FUR CHEMIE | 2020年 / 151卷 / 05期
关键词：
Magnetic properties; Crystal structure; Transition metals compounds; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; SINGLE-CHAIN; ARCHITECTURES; CORE; DICARBOXYLATE; RELAXATION; COBALT(II); COMPLEXES; LIGANDS;
D O I：
10.1007/s00706-020-02606-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A paramagnetic compound, [Co-2(p-bdc)(4)(dfdp)(4))](n) (p-bdc = 1,4-benzenedicarboxylic acid, dfdp = 4,4 '-(2,5-difluoro-1,4-phenylene)dipyridine), has been solvothermally synthesized and fully characterized. The compound displays a 3D twofold interpenetrating framework with pcu nets with point symbol {4(12)center dot 6(3)}. Thermogravimetric analysis indicates the compound has good thermal stability in solid states. The UV-Vis spectrum demonstrates that the compound has two absorption peaks at 320 and 470 nm. Magnetic investigation shows that the compound exhibits regular Curie behavior. Graphic abstract
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收藏
页码：751 / 756
页数：6
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