Synthesis, crystal structure, thermal stability, and magnetic properties of a paramagnetic Co(II) [Co2(p-bdc)4(dfdp)4)]n derived from 1,4-benzenedicarboxylic acid and 4,4′-(2,5-difluoro-1,4-phenylene)dipyridine

被引：0

作者：

Yang, Xiaolin ^{[1
]}

Yang, Yi ^{[1
]}

Tu, Yuyu ^{[2
]}

Lin, Lan ^{[3
]}

Wang, Fei ^{[1
]}

Yin, Rui ^{[2
]}

Jiang, Tianyu ^{[1
]}

Chen, Ziying ^{[1
]}

Ju, Yichun ^{[3
]}

机构：

[1] Changzhou Vocat Inst Engn, Changzhou 213164, Jiangsu, Peoples R China

[2] Nanjing Med Univ, Sch Med Imaging, Nanjing 211166, Peoples R China

[3] Nanjing Med Univ, Sch Pharm, Key Lab Cardiovasc & Cerebrovasc Med, Nanjing 211166, Peoples R China

来源：

MONATSHEFTE FUR CHEMIE | 2020年 / 151卷 / 05期

关键词：

Magnetic properties; Crystal structure; Transition metals compounds; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; SINGLE-CHAIN; ARCHITECTURES; CORE; DICARBOXYLATE; RELAXATION; COBALT(II); COMPLEXES; LIGANDS;

D O I：

10.1007/s00706-020-02606-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A paramagnetic compound, [Co-2(p-bdc)(4)(dfdp)(4))](n) (p-bdc = 1,4-benzenedicarboxylic acid, dfdp = 4,4 '-(2,5-difluoro-1,4-phenylene)dipyridine), has been solvothermally synthesized and fully characterized. The compound displays a 3D twofold interpenetrating framework with pcu nets with point symbol {4(12)center dot 6(3)}. Thermogravimetric analysis indicates the compound has good thermal stability in solid states. The UV-Vis spectrum demonstrates that the compound has two absorption peaks at 320 and 470 nm. Magnetic investigation shows that the compound exhibits regular Curie behavior. Graphic abstract

引用

页码：751 / 756

页数：6

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