The evaporation of n-hexadecane from highly oriented pyrolytic graphite studied by atomic force microscopy

被引:11
作者
Martin, DS
Weightman, P
Gauntlett, JT
机构
[1] Univ Liverpool, IRC Surface Sci, Liverpool L69 3BX, Merseyside, England
[2] Shell Res & Technol Ctr, Chester CH1 3SH, Cheshire, England
基金
英国工程与自然科学研究理事会;
关键词
alkanes; atomic force microscopy; evaporation; highly oriented pyrolytic graphite; physical adsorption;
D O I
10.1016/S0039-6028(98)00717-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The evaporation of n-hexadecane from highly oriented pyrolytic graphite (HOPG) has been investigated using tapping mode atomic force microscopy. Four evaporation times of 5, 10, 15, and 25 min have been studied. The same gross features are observed for all evaporation times, namely two types of isolated features located on the terraces and continuous features associated with steps on the graphite surface. Extensive measurements have been performed on the observed features allowing a detailed comparison between evaporation times;Models describing the molecular orientations within the features are proposed. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:390 / 405
页数:16
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