7′-(4-Bromophenyl)-5′,6′,7′,7a′-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2"-indan]-1,3,1"-trione

被引：3
|
作者：
Wei, Ang Chee [2 ]
Ali, Mohamed Ashraf [2 ]
Yoon, Yeong Keng [2 ]
Quah, Ching Kheng [1 ]
Fun, Hoong-Kun [1 ]
机构：
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Inst Res Mol Med, Usm 11800, Penang, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 17.7; mean σ(C-C) = 0.005 Å; R factor = 0.044; single-crystal X-ray study; T = 296 K; wR factor = 0.136;
D O I：
10.1107/S1600536811046514
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C28H20BrNO3S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)degrees with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)degrees. The molecular structure features an intramolecular C-H center dot center dot center dot O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：O3274 / U555
页数：12
相关论文
共 50 条
  • [1] 7′-[4-(Trifluoromethyl)phenyl]-5′,6′,7′,7a′-tetrahydrodispiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2"-indan]-1,3,1"-trione
    Wei, Ang Chee
    Ali, Mohamed Ashraf
    Ismail, Rusli
    Quah, Ching Kheng
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3293 - U1055
  • [2] 7′-Phenyl-5′,6′,7′,7a′-tetrahydrodipiro[indan-2,5′-pyrrolo[1,2-c][1,3]thiazole-6′,2"-indan]-1,3,1"-trione
    Wei, Ang Chee
    Ali, Mohamed Ashraf
    Choon, Tan Soo
    Quah, Ching Kheng
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3218 - U1944
  • [3] 7'-(2,5-Dimethoxyphenyl)10,30,50,60,70,7a'- hexahydrodispiro[indan-2,50- pyrrolo[1,2-c][1,3]thiazole-6',2''-indan]-1,3,1''-trione
    Wei, Ang Chee
    Ali, Mohamed Ashraf
    Choon, Tan Soo
    Razak, Ibrahim Abdul
    Arshad, Suhana
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O560 - U1111
  • [4] 5"-(4-Methoxybenzylidene)-7′-(4-methoxyphenyl)-1"-methyl-5′,6′,7′,7a′-tetrahydrodispiro[acenaphthene-1,5′-pyrrolo[1,2-c][1,3]thiazole-6′,3"-piperidine]-2,4"-dione
    Suresh, J.
    Vishnupriya, R.
    Kumar, R. Ranjith
    Sivakumar, S.
    Lakshman, P. L. Nilantha
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3210 - U851
  • [5] 1 ''-Allyl-5 ''-(4-methoxybenzylidene)-7 '-(4-methoxyphenyl)-1 ',3 ',5 ',6 ',7 ',7a '-hexa-hydrodispiro[acenaphthylene-1,5 '-pyrrolo[1,2-c][1,3]thiazole-6 ',3 ''-piperidine]-2,4 ''(1H)-dione
    Almansour, Abulrahman I.
    Kumar, Raju Suresh
    Arumugam, Natarajan
    Nagalakshmi, R. A.
    Suresh, J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1345 - +
  • [6] 7'-(Naphthalen-1-yl)-5"-[(naphthalen-2-yl) methylidene]-1',3',5',6',7',7a'-hexa-hydrodispiro[acenaphthene-1,5'pyrrolo[1,2-c] thiazole-6',3"-piperidine]-2(1H),4"-dione
    Suresh, J.
    Vishnupriya, R.
    Kumar, R. Ranjith
    Sivakumar, S.
    Lakshman, P. L. Nilantha
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O858 - U3109
  • [7] 5"-(4-Nitrobenzylidene)-7'-(4-nitrophenyl)-1"-methyl-1',3',5',6',70'7a'-hexahydro-dispiro[acenaphthylene-1,5'-pyrrolo-[1,2-c][1,3]thiazole-6',3"-piperidine]-2,4"(1H)-dione including an unknown solvate
    Vishnupriya, R.
    Suresh, J.
    Sivakumar, S.
    Kumar, R. Ranjith
    Lakshman, P. L. Nilantha
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1208 - +
  • [8] Ethyl 7'-(6-benzyloxy-2,2-dimethyltetrahydrofuro[3,2-d][1,3] dioxol-5-yl)-2-oxo5',6',7',7a'-tetrahydro-1'H, 2H-spiro[acenaphthylene-1,5'- pyrrolo[1,2-c][1,3]thiazole]-6'-carboxylate
    Jagadeesan, G.
    Sethusankar, K.
    Prasanna, R.
    Raghunathan, R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02505 - +
  • [9] Ethyl (1R,1′S,2′S,7a′R)-2-oxo-1′-[(3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3aH-bis[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl]-1′,2′,5′,6′,7′,7a′-hexahydro-2H-spiro[acenaphthylene-1,3′-pyrrolizine]-2′-carboxylate
    Jagadeesan, G.
    Sethusankar, K.
    Prasanna, R.
    Raghunathan, R.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O382 - U470
  • [10] 7-(4-Bromophenyl)-9-phenyl-7H-pyrrolo[3,2-e]tetrazolo[1,5-c]pyrimidine
    Jotani, Mukesh M.
    Shah, Rina D.
    Jasinski, Jerry P.
    Butcher, Ray J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O574 - U4653
12345