catena-Poly[[diaqualithium]-μ-[rac-cis-(2-carboxycyclohexane-1-carboxylato-κ2O1:O2]]

被引：0
|
作者：
Smith, Graham [1 ]
Wermuth, Urs D. [1 ]
Williams, Michael L. [2 ]
机构：
[1] Queensland Univ Technol, Fac Sci & Technol, Brisbane, Qld 4001, Australia
[2] Griffith Univ, Sch Biomol & Phys Sci, Nathan, Qld 4111, Australia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金：
澳大利亚研究理事会;
关键词：
data-to-parameter ratio = 15.3; mean σ(C-C) = 0.002 Å; R factor = 0.045; single-crystal X-ray study; T = 200 K; wR factor = 0.134;
D O I：
10.1107/S1600536811045077
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the structure of the title compound, [Li(C8H11O4)(H2O)(2)](n), the distorted tetrahadral LiO4 coordination sphere comprises two water molecules and two carboxyl O-atom donors from separate bridging cis-2-carboxycyclohexane-1-carboxylate monoanions [Li-O = 1.887 (4)-1.946 (3) angstrom], giving chain substructures which extend along [010]. Water-water and water-carboxyl O-H center dot center dot center dot O hydrogen bonds stabilize these chain structures and provide interchain links, resulting in a two-dimensional layered structure extending parallel to (100).
引用
收藏
页码：M1658 / U1922
页数：11
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