Supramolecular solvent microextraction and ultra-performance liquid chromatography-tandem mass spectrometry combination for the preconcentration and determination of malathion in environmental samples

被引：28

作者：

ALOthman, Zeid A. ^{[1
,2
]}

Yilmaz, Erkan ^{[3
,4
]}

Habila, Mohamed A. ^{[1
,2
]}

Ghfar, Ayman A. ^{[1
,2
]}

Alhenaki, Bushra ^{[1
,5
]}

Soylak, Mustafa ^{[6
]}

Ahmed, A. Y. Badjah Hadj ^{[1
,2
]}

机构：

[1] King Saud Univ, Dept Chem, Adv Mat Res Chair, Coll Sci, POB 2455, Riyadh 11451, Saudi Arabia

[2] King Saud Univ, Dept Chem, Coll Sci, Riyadh 11451, Saudi Arabia

[3] Erciyes Univ, Dept Analyt Chem, Fac Pharm, TR-38039 Kayseri, Turkey

[4] Erciyes Univ, Nanotechnol Res Ctr ERNAM, TR-38039 Kayseri, Turkey

[5] Qassim Univ, Dept Chem, Sci & Art Coll Buraydah, Buraydah, Saudi Arabia

[6] Erciyes Univ, Dept Chem, Sci Fac, TR-38039 Kayseri, Turkey

来源：

DESALINATION AND WATER TREATMENT | 2019年 / 144卷

关键词：

Supramolecular solvent; Microextraction; Malathion; Heptanol; Tetrahydrofuran; Ultra-performance liquid chromatography-tandem mass spectrometry; SOLID-PHASE EXTRACTION; PESTICIDE-RESIDUES; CARBON; COPPER; LEAD; MS;

D O I：

10.5004/dwt.2019.23574

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A supramolecular solvent microextraction method was used for the fast and selective preconcentration separation of malathion, and then ultra-performance liquid chromatography-tandem mass spectrometry was applied for the detection of malathion. The supramolecular solvent is a suitable medium for malathion collection from the sample extract. The results showed that the quantitative recovery of malathion was obtained at pH 4 with heptanol-tetrahydrofuran as the supramolecular solvent. The preconcentration of malathion by the developed microextraction method was established within 10 min. The limit of detection and the quantification limit were 1.4 and 4.2 mu g/L, respectively. A preconcentration factor of 40 was obtained, and the relative standard deviation was <7%. The developed supramolecular solvent microextraction method was applied for different real samples, including fruits, vegetables, and water samples.

引用

收藏

页码：166 / 171

页数：6

相关论文

共 20 条

[1] Solid phase extraction of Cd(II), Pb(II), Zn(II) and Ni(II) from food samples using multiwalled carbon nanotubes impregnated with 4-(2-thiazolylazo)resorcinol [J].

ALOthman, Zeid A. ;

Habila, Mohamed ;

Yilmaz, Erkan ;

Soylak, Mustafa .

MICROCHIMICA ACTA, 2012, 177 (3-4) :397-403

[2] Accurate and sensitive determination of selected hormones, endocrine disruptors, and pesticides by gas chromatography-mass spectrometry after the multivariate optimization of switchable solvent liquid-phase microextraction [J].

Chormey, Dotse Selali ;

Bodur, Suleyman ;

Baskin, Dilges ;

Firat, Merve ;

Bakirdere, Sezgin .

JOURNAL OF SEPARATION SCIENCE, 2018, 41 (14) :2895-2902

[3] Organophosphorus insecticides chlorpyrifos and diazinon and oxidative stress in neuronal cells in a genetic model of glutathione deficiency [J].

Giordano, Gennaro ;

Afsharinejad, Zhara ;

Guizzetti, Marina ;

Vitalone, Annabella ;

Kavanagh, Terrance J. ;

Costa, Lucio G. .

TOXICOLOGY AND APPLIED PHARMACOLOGY, 2007, 219 (2-3) :181-189

[4] Immunotoxicity and hepatic function evaluation in Nile tilapia (Oreochromis niloticus) exposed to diazinon [J].

Giron-Perez, Manuel Ivan ;

Anne, Santerre ;

Fabiola, Gonzalez-Jaime ;

Josefina, Casas-Solis ;

Marcela, Hernandez-Coronado ;

Jorge, Peregrina-Sandoval ;

Akiro, Takemura ;

Galina, Zaitseva .

FISH & SHELLFISH IMMUNOLOGY, 2007, 23 (04) :760-769

[5] Mercaptobenzothiazole-functionalized magnetic carbon nanospheres of type Fe3O4@SiO2@C for the preconcentration of nickel, copper and lead prior to their determination by ICP-MS [J].

Habila, Mohamed A. ;

ALOthman, Zeid A. ;

El-Toni, Ahmed Mohamed ;

Labis, Joselito Puzon ;

Li, Xiaomin ;

Zhang, Fan ;

Soylak, Mustafa .

MICROCHIMICA ACTA, 2016, 183 (08) :2377-2384

[6] Synthesis and application of Fe3O4@SiO2@TiO2 for photocatalytic decomposition of organic matrix simultaneously with magnetic solid phase extraction of heavy metals prior to ICP-MS analysis [J].

Habila, Mohamed A. ;

ALOthman, Zeid A. ;

El-Toni, Ahmed Mohamed ;

Labis, Joselito Puzon ;

Soylak, Mustafa .

TALANTA, 2016, 154 :539-547

[7] Activated carbon from waste as an efficient adsorbent for malathion for detection and removal purposes [J].

Habila, Mohamed Abdelaty ;

ALOthman, Zeid Abdullah ;

Al-Tamrah, Saad A. ;

Ghafar, Ayman Abdel ;

Soylak, Mustafa .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 32 :336-344

[8] A fast and green preconcentration method based on surfactant ion pair-switchable solvent dispersive liquid-liquid microextraction for determination of phenazopyridine in pharmaceutical and biological samples [J].

Hamid, Yahya ;

Fat'hi, Mohammad Reza .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2018, 15 (08) :1813-1820

[9]

Lofty H. M., 2013, Bulletin of the Faculty of Pharmacy, Cairo University, V51, P255, DOI 10.1016/j.bfopcu.2013.08.001

[10] A novel and sensitive kinetic method for the determination of malathion using chromogenic reagent [J].

Pandey, Garima Pravin ;

Singh, Ajaya K. ;

Deshmukh, Lata ;

Prasad, Surendra ;

Paliwal, L. J. ;

Asthana, Anupama ;

Mathew, Sunitha B. .

MICROCHEMICAL JOURNAL, 2014, 113 :83-89