Alternating hydrophilic and hydrophobic pockets in the channel structures of organostannoxane prismanes: Preferential confinement of guest molecules

被引:47
作者
Chandrasekhar, V [1 ]
Thilagar, P
Bickley, JF
Steiner, A
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Liver Unit, Dept Chem, Liverpool L69 7ZD, Merseyside, England
关键词
D O I
10.1021/ja052776b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hydroxyl-rich hexameric organooxotin prismane has been prepared by reaction of n-BuSn(O)OH with 9-hydroxy-9-fluorenecarboxylic acid. The supramolecular structure of this cage shows channels with hydrophobic and hydrophilic segments, which selectively entrap guest molecules. Copyright © 2005 American Chemical Society.
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页码:11556 / 11557
页数:2
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