Heterogeneous and homogeneous catalysis for the hydrogenation of carboxylic acid derivatives: history, advances and future directions

被引：430

作者：

Pritchard, James ^{[1
]}

Filonenko, Georgy A. ^{[1
,2
]}

van Putten, Robbert ^{[1
]}

Hensen, Emiel J. M. ^{[1
,2
]}

Pidko, Evgeny A. ^{[1
,2
]}

机构：

[1] Eindhoven Univ Technol, Inorgan Mat Chem Grp, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Eindhoven Univ Technol, Inst Complex Mol Syst, NL-5600 MB Eindhoven, Netherlands

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 11期

关键词：

AQUEOUS-PHASE HYDROGENATION; RHENIUM-ALUMINA CATALYSTS; METAL HYDRIDE CATALYSTS; RUTHENIUM-TIN CATALYSTS; SELECTIVE HYDROGENATION; DIMETHYL OXALATE; LEVULINIC ACID; GAMMA-VALEROLACTONE; HIGHLY EFFICIENT; METHYL OLEATE;

D O I：

10.1039/c5cs00038f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic reduction of carboxylic acid derivatives has witnessed a rapid development in recent years. These reactions, involving molecular hydrogen as the reducing agent, can be promoted by heterogeneous and homogeneous catalysts. The milestone achievements and recent results by both approaches are discussed in this Review. In particular, we focus on the mechanistic aspects of the catalytic hydrogenation and highlight the bifunctional nature of the mechanism that is preferred for supported metal catalysts as well as homogeneous transition metal complexes.

引用

页码：3808 / 3833

页数：26

共 210 条

[1] Analysis of Kinetics and Reaction Pathways in the Aqueous-Phase Hydrogenation of Levulinic Acid To Form γ-Valerolactone over Ru/C [J].