Development of crayfish protein-PCL biocomposite material processed by injection moulding

被引:23
作者
Felix, M. [1 ]
Romero, A. [1 ]
Martin-Alfonso, J. E. [1 ]
Guerrero, A. [1 ]
机构
[1] Univ Seville, Fac Quim, Dept Ingn Quim, E-41012 Seville, Spain
关键词
Polymer-matrix composites (PMCs); Rheological properties; Thermomechanical; Injection moulding; GLUTEN-BASED BIOPLASTICS; BLENDS; PLASTICIZERS; MORPHOLOGY; POLYMERS; RHEOLOGY; FLOUR; WATER;
D O I
10.1016/j.compositesb.2015.03.057
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A combination of crayfish flour (CF, with 60% protein) and Polycaprolactone (PCL) was successfully used to prepare biocomposites by a process that consists of two stages: mixing with glycerol (GL) as plasticizer and injection moulding of CF/GL/PCL blends. Mixing rheometry and Differential Scanning Calorimetry (DSC) measurements were found to be useful to select suitable injection moulding conditions. A remarkable enhancement in mechanical properties was found for PCL containing systems, even when crystalline structure remains unaltered. PCL yields a dominant contribution to the elastic response and confer a higher ability to absorb energy before rupture, but also the protein/plasticiser ratio must be considered. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:291 / 297
页数:7
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