Hypervalent Iodine Reagents and Green Chemistry

被引：162

作者：

Yusubov, Mekhman S. ^{[2
,3
]}

Zhdankin, Viktor V. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA

[2] Siberian State Med Univ, Tomsk 634050, Russia

[3] Tomsk Polytech Univ, Tomsk 634050, Russia

来源：

CURRENT ORGANIC SYNTHESIS | 2012年 / 9卷 / 02期

基金：

美国国家科学基金会;

关键词：

Hypervalent iodine; green chemistry; polymer-supported reagents; catalysis; oxidation; M-CHLOROPERBENZOIC ACID; M-IODOSYLBENZOIC ACID; IN-SITU GENERATION; CONVENIENT RECYCLABLE REAGENT; SULFONATE MEDIATED SYNTHESIS; HIGHLY SELECTIVE OXIDATION; DIRECT ALPHA-HYDROXYLATION; FLUOROUS ALKYL IODIDES; RAY CRYSTAL-STRUCTURE; IONIC LIQUID;

D O I：

10.2174/157017912799829021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent advances in the development of environmentally friendly recyclable reagents and catalytic systems based on hypervalent iodine are discussed. The review covers the following topics of active current research: polymer-supported iodine(III) and iodine(V) oxidants, recyclable monomeric hypervalent iodine(III) reagents, reactions of hypervalent iodine in solid state, application of water or recyclable organic solvents in these reactions, and catalytic systems based on hypervalent iodine compounds. These efficient and eco-friendly reagents and catalytic systems are now widely used in organic synthesis for various oxidative transformations of organic substrates.

引用

页码：247 / 272

页数：26

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