Energy conversion from electrolyte concentration gradient using charged nano-pores

Power generation based on the reversed electro-dialysis (RED) cell is studied both numerically and experimentally in this work. The membrane that separates the concentrated and dilute electrolytes is treated as a charged nano-pore array. Both numerical and experimental results show that the RED cell performance is similar to the typical electrochemical cell having a linearly varied current-voltage relation. The open circuit voltage and short-circuit current depend on the ion selectivity of the nano-pore membrane, which is related to the concentration ratio, pore surface charge density, and pore size. The highest energy conversion efficiencies are approximately 48% and 24% from numerical predictions and experimental measurements, respectively. The reason for this discrepancy is attributed to the inhomogenous pore size and surface charge density distributions of the Al2O3 membrane used in these experiments.