Preparation of Al, Ti, Zr-perfluoroheptanoate compounds and their use in ring opening polymerization

被引：16

作者：

Yalcin, Gamze ^{[1
]}

Yildiz, Ufuk ^{[1
]}

Kayan, Asgar ^{[1
]}

机构：

[1] Kocaeli Univ, Dept Chem, TR-41380 Kocaeli, Turkey

来源：

APPLIED CATALYSIS A-GENERAL | 2012年 / 423卷

关键词：

Catalyst; Metal alkoxides; Perfluoroheptanoate; Ring-opening; STRUCTURAL-CHARACTERIZATION; METAL ALKOXIDES; ACID; COMPLEXATION; CONDENSATION; HYDROLYSIS; CATALYSTS; POLYMERS; LACTIDE; FILMS;

D O I：

10.1016/j.apcata.2012.02.042

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Aluminum, titanium and zirconium perfluoroheptanoate (PFH) were prepared by reaction of Al, Ti and Zr-alkoxides with perfluoroheptanoic acid (PFHA) in alcohol. All compounds were characterized by NMR spectroscopy, FTIR, MS and elemental analysis and used in polymerization of 3-glycidyloxypropyltrimethoxysilane (GPTS) in order to see their catalytic activity over epoxides. These catalysts were effective in ring opening of epoxide. Poly-GPTS was characterized by H-1, C-13 NMR and gel permeation chromatography (GPC). (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：205 / 210

页数：6

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