Momordica Charantia pericarp derived activated carbon with dual redox additive electrolyte for high energy density supercapacitor devices

被引:42
作者
Aparna, M. L. [1 ,2 ,3 ]
Rao, G. Ranga [1 ,3 ]
Thomas, Tiju [2 ,3 ]
机构
[1] Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India
[2] Indian Inst Technol Madras, Dept Met & Mat Engn, Chennai 600036, Tamil Nadu, India
[3] Indian Inst Technol Madras, DST Solar Energy Harnessing Ctr, Chennai 600036, Tamil Nadu, India
关键词
Bitter gourd pericarp; Activated carbon; Energy density; Supercapacitors; Dual redox additive electrolyte; HIERARCHICAL POROUS CARBON; HIGH-PERFORMANCE SUPERCAPACITORS; SURFACE-AREA; TEMPLATE SYNTHESIS; OXYGEN REDUCTION; NITROGEN; WASTE; SHELL; FRAMEWORKS; NANOSHEETS;
D O I
10.1016/j.est.2022.104048
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Activated carbon with porous structures attracted much attention for supercapacitor applications due to their viability, sustainability, and eco-friendliness. In particular, decentralized and sustainable production of materials related to energy technologies would be enabled through bio-source derived materials. This is the first report on Momordica Charantia as a bio precursor for making electrode material. Herein, KOH-treated porous activated carbon was prepared under different activation temperatures using the pericarp of Momordica Charantia. The activated carbon synthesized at an activation temperature of 900 celcius showed a high specific surface area of 1126 m(2) g(-1). It exhibited a specific capacitance of 186 F g(-1) at 1 A g(-1). Symmetric supercapacitor device fabricated delivered an energy density of 8 Wh kg(-1) at a power density of 750 W kg(-1) with 98% capacitance retention after 5000 cycles in 1 M H2SO4. A further improvement of energy density to a maximum of 23 Wh kg(-1) and a maximum power density of 6000 W kg(-1) was achieved using dual redox mediators (KI + HQ) in H(2)SO(4)due to the redox activity of the I-2/I- and Q/HQ redox species at the positive electrode.
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页数:14
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