Monoterpene glycosides isolated from Fadogia agrestis

被引:10
作者
Anero, Regina [1 ]
Diaz-Lanza, Ana [1 ]
Ollivier, Evelyne [2 ]
Baghdikian, Beatrice [2 ]
Balansard, Guy [2 ]
Bernabe, Manuel [3 ]
机构
[1] Univ Alcala de Henares, Dept Farmacognosia, Fac Farm, Madrid 28871, Spain
[2] Univ Aix Marseille 2, Lab Pharmacognosie, Fac Pharm, F-13385 Marseille 5, France
[3] CSIC, Inst Quim Organ, Dept Quim Organ Biol, E-28006 Madrid, Spain
关键词
Fadogia agrestis; Rubiaceae; monoterpene glycosides;
D O I
10.1016/j.phytochem.2007.09.024
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Six monoterpene glycosides were isolated from Fadogia agrestis. Their structures were elucidated using a combination of mass spectroscopy, 1D- and 2D-homo- and hetero-NMR spectroscopy and chemical analysis, and established as being derivatives of 2,6-dimethyl-2(E),6(Z)-octadiene-1,8-diol containing from two to four units of rhamnopyranose and, three of them, one or two additional units of glucopyranose. In three of the compounds an acyl group of 8-hydroxy-2,6-dimethyl-2(E),6(Z)-octadienoyl was found esterifying the O-2 position of one of the units of rhamnopyranose. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:805 / 811
页数:7
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