Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides

被引：77

作者：

Smith, DK ^{[1
]}

Diederich, F ^{[1
]}

机构：

[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 22期

关键词：

D O I：

10.1039/a806596i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantiomerically pure dendritic cleft receptors (dendroclefts) with a 9,9'-spirobi[9H-fluorene] core are prepared for the recognition of glucopyranosides by I-I-bonding in CDCl(3); the enantio- and diastereo-selectivities in the complexation processes are modulated by the presence of the dendritic shell.

引用

页码：2501 / 2502

页数：2

共 18 条

[1] ENANTIOSELECTIVE COMPLEXATION OF CHIRAL DICARBOXYLIC-ACIDS IN CLEFTS OF FUNCTIONALIZED 9,9'-SPIROBIFLUORENES
ALCAZAR, V
DIEDERICH, F
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (11): : 1521 - 1523
[2] DIASTEREOSELECTIVE AND ENANTIO-SELECTIVE BINDING OF OCTYL GLUCOSIDES BY AN ARTIFICIAL RECEPTOR
BHATTARAI, KM
BONARLAW, RP
DAVIS, AP
MURRAY, BA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) : 752 - 754
[3] POLYOL RECOGNITION BY A STEROID-CAPPED PORPHYRIN - ENHANCEMENT AND MODULATION OF MISFIT GUEST BINDING BY ADDED WATER OR METHANOL
BONARLAW, RP
SANDERS, JKM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) : 259 - 271
[4] MOLECULAR CLEFTS DERIVED FROM 9,9'-SPIROBI[9H-FLUORENE] FOR ENANTIOSELECTIVE COMPLEXATION OF PYRANOSIDES AND DICARBOXYLIC-ACIDS
CUNTZE, J
OWENS, L
ALCAZAR, V
SEILER, P
DIEDERICH, F
[J]. HELVETICA CHIMICA ACTA, 1995, 78 (02) : 367 - 390
[5] A NEW CONVERGENT APPROACH TO MONODISPERSE DENDRITIC MACROMOLECULES
HAWKER, CJ
FRECHET, JMJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (15) : 1010 - 1013
[6] Molecular recognition of beta-ribofuranosides by synthetic polypyridine-macrocyclic receptors
Inouye, M
Miyake, T
Furusyo, M
Nakazumi, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (50) : 12416 - 12425
[7] ISSBERNER J, 1994, ANGEW CHEM INT EDIT, V33, P2413
[8] Saccharide sensing with molecular receptors based on boronic acid
James, TD
Sandanayake, KRAS
Shinkai, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (17) : 1910 - 1922
[9] A saccharide 'sponge'. Synthesis and properties of a dendritic boronic acid
James, TD
Shinmori, H
Takeuchi, M
Shinkai, S
[J]. CHEMICAL COMMUNICATIONS, 1996, (06) : 705 - 706
[10] HIGHLY COOPERATIVE BINDING OF ALKYL GLUCOPYRANOSIDES TO THE RESORCINOL CYCLIC TETRAMER DUE TO INTRACOMPLEX GUEST GUEST HYDROGEN-BONDING - SOLVOPHOBICITY SOLVOPHILICITY CONTROL BY AN ALKYL GROUP OF THE GEOMETRY, STOICHIOMETRY, STEREOSELECTIVITY, AND COOPERATIVITY
KIKUCHI, Y
TANAKA, Y
SUTARTO, S
KOBAYASHI, K
TOI, H
AOYAMA, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) : 10302 - 10306

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