Current-Voltage Characteristics of Bulk Heterojunction Organic Solar Cells: Connection Between Light and Dark Curves

被引：61

作者：

Boix, Pablo P. ^{[1
]}

Guerrero, Antonio ^{[1
]}

Marchesi, Luis F. ^{[1
,2
]}

Garcia-Belmonte, Germa ^{[1
]}

Bisquert, Juan ^{[1
]}

机构：

[1] Univ Jaume 1, Dept Fis, Photovolta & Optoelect Devices Grp, ES-12071 Castellon de La Plana, Spain

[2] Univ Fed Sao Carlos, LIEC, BR-13560 Sao Carlos, SP, Brazil

来源：

ADVANCED ENERGY MATERIALS | 2011年 / 1卷 / 06期

关键词：

organic photovoltaics; recombination resistance; current-voltage; impedance spectroscopy; NONGEMINATE RECOMBINATION; FILL FACTOR; COLLECTION; LOSSES; STATES;

D O I：

10.1002/aenm.201100334

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A connection is established between recombination and series resistances extracted from impedance spectroscopy and current-voltage curves of polythiophene:fullerene organic solar cells. Recombination is shown to depend exclusively on the (Fermi level) voltage, which allows construction of the current-voltage characteristics in any required conditions based on a restricted set of measurements. The analysis highlights carrier recombination current as the determining mechanism of organic solar cell performance.

引用

页码：1073 / 1078

页数：6

共 29 条

[1] Physical chemical principles of photovoltaic conversion with nanoparticulate, mesoporous dye-sensitized solar cells [J].

Bisquert, J ;

Cahen, D ;

Hodes, G ;

Rühle, S ;

Zaban, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (24) :8106-8118

[2] Simulation of Steady-State Characteristics of Dye-Sensitized Solar Cells and the Interpretation of the Diffusion Length [J].

Bisquert, Juan ;

Mora-Sero, Ivan .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (01) :450-456

[3] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[4] Recombination in polymer-fullerene bulk heterojunction solar cells [J].

Cowan, Sarah R. ;

Roy, Anshuman ;

Heeger, Alan J. .

PHYSICAL REVIEW B, 2010, 82 (24)

[5] A RECIPROCITY THEOREM FOR CHARGE COLLECTION [J].

DONOLATO, C .

APPLIED PHYSICS LETTERS, 1985, 46 (03) :270-272

[6] Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy [J].

Fabregat-Santiago, Francisco ;

Garcia-Belmonte, Germa ;

Mora-Sero, Ivan ;

Bisquert, Juan .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (20) :9083-9118

[7] Influence of the Intermediate Density-of-States Occupancy on Open-Circuit Voltage of Bulk Heterojunction Solar Cells with Different Fullerene Acceptors [J].

Garcia-Belmonte, Germa ;

Boix, Pablo P. ;

Bisquert, Juan ;

Lenes, Martijn ;

Bolink, Henk J. ;

La Rosa, Andrea ;

Filippone, Salvatore ;

Martin, Nazario .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (17) :2566-2571

[8] Open-circuit voltage limit caused by recombination through tail states in bulk heterojunction polymer-fullerene solar cells [J].

Garcia-Belmonte, Germa ;

Bisquert, Juan .

APPLIED PHYSICS LETTERS, 2010, 96 (11)

[9] Simultaneous determination of carrier lifetime and electron density-of-states in P3HT:PCBM organic solar cells under illumination by impedance spectroscopy [J].

Garcia-Belmonte, Germa ;

Boix, Pablo P. ;

Bisquert, Juan ;

Sessolo, Michele ;

Bolink, Henk J. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (02) :366-375

[10] Solar cell efficiency tables (version 37) [J].

Green, Martin A. ;

Emery, Keith ;

Hishikawa, Yoshihiro ;

Warta, Wilhelm .

PROGRESS IN PHOTOVOLTAICS, 2011, 19 (01) :84-92

← 1 2 3 →