Novel nonenzymatic hydrogen peroxide sensor based on Fe3O4/PPy/Ag nanocomposites

被引:29
作者
Qi, Chengcheng [1 ]
Zheng, Jianbin [1 ]
机构
[1] NW Univ Xian, Inst Analyt Sci, Shaanxi Prov Key Lab Electroanalyt Chem, Xian 710069, Peoples R China
基金
美国国家科学基金会;
关键词
Nonenzymatic sensor; Silver nanoparticles; Hydrogen peroxide; Ferroferric oxide; Polypyrrole; REDUCED GRAPHENE OXIDE; H2O2; DETECTION; AG NANOPARTICLES; ELECTROCHEMICAL PROPERTIES; SILVER NANOPARTICLES; POLYPYRROLE; ELECTRODES; COLLOIDS; NANOSPHERES; NANOSHEETS;
D O I
10.1016/j.jelechem.2015.04.004
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Fe3O4/PPy/Ag nanocomposites with core/shell/shell structure were prepared and used for fabricating nonenzymatic H2O2 sensor. The nanocomposites were prepared with a three-step process, and proved by characterizations such as transmission electron microscopic, X-ray diffraction and X-ray photoelectron spectroscopy. The electrochemical investigation revealed that the composites had excellent catalytic property toward H2O2. The sensor could detect H2O2 with a wide linear range from 5 mu M to 11.5 mM, and a low detection limit of 1.7 mu M. Additionally, the sensor exhibited long-term stability, good reproducibility and anti-interference. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:53 / 58
页数:6
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