Recent Advances in Voltammetry

被引：171

作者：

Batchelor-McAuley, Christopher ^{[1
]}

Kaetelhoen, Enno ^{[1
]}

Barnes, Edward O. ^{[1
]}

Compton, Richard G. ^{[1
]}

Laborda, Eduardo ^{[2
]}

Molina, Angela ^{[2
]}

机构：

[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Univ Murcia, Dept Quim Fis, Fac Quim, E-30100 Murcia, Spain

来源：

CHEMISTRYOPEN | 2015年 / 4卷 / 03期

基金：

欧洲研究理事会;

关键词：

cyclic voltammetry; electrochemistry; electron transfer; kinetics; mass transport; nanoparticle electrochemistry; stripping voltammetry; SQUARE-WAVE VOLTAMMETRY; TEMPERATURE IONIC LIQUIDS; DIFFERENTIAL-PULSE VOLTAMMETRY; HETEROGENEOUS ELECTRON-TRANSFER; LINEAR SWEEP VOLTAMMETRY; POTENTIAL-STEP CHRONOAMPEROMETRY; WEAKLY SUPPORTED MEDIA; MARCUS-HUSH THEORY; SINGLE-NANOPARTICLE COLLISIONS; ANODIC-STRIPPING VOLTAMMETRY;

D O I：

10.1002/open.201500042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemical processes, voltammetry in ionic liquids, the development and interpretation of theories of electron transfer (Butler-Volmer and Marcus-Hush), advances in voltammetric pulse techniques, stochastic random walk models of diffusion, the influence of migration under conditions of low support, voltammetry at rough and porous electrodes, and nanoparticle electrochemistry. The review of the latter field encompasses both the study of nanoparticle-modified electrodes, including stripping voltammetry and the new technique of 'nano-impacts'.

引用

页码：224 / 260

页数：37

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