Synthesis of highly porous borazine-linked polymers and their application to H2, CO2, and CH4 storage

被引：76

作者：

Jackson, Karl T. ^{[1
]}

Rabbani, Mohammad G. ^{[1
]}

Reich, Thomas E. ^{[1
]}

El-Kaderi, Hani M. ^{[1
]}

机构：

[1] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA

来源：

POLYMER CHEMISTRY | 2011年 / 2卷 / 12期

关键词：

HYDROGEN-STORAGE; ORGANIC FRAMEWORKS; BORON-NITRIDE; INTRINSIC MICROPOROSITY; MECHANISM; DESIGN; NETWORKS; CAPTURE; SERIES; B-11;

D O I：

10.1039/c1py00374g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of highly porous borazine-linked polymers (BLPs) and their gas uptakes are reported. BLPs exhibit high surface areas up to 2866 m(2) g(-1) and can store significant amounts of H-2 (1.93 wt%) and CO2 (12.8 wt%) at 77 K and 273 K, respectively at 1.0 bar with respective isosteric heats of adsorption of 6.0 and 25.2 kJ mol(-1).

引用

页码：2775 / 2777

页数：3

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