Photosensitization of multiwalled carbon nanotube scaffolds with ZnO quantum dots for photovoltaic applications

被引:6
作者
Dutta, M. [1 ]
Basak, D. [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, India
关键词
Quantum dots; ZnO; Composite; Multiwalled carbon nanotubes; Photosensitization; Photovoltaic solar cell; Energy conversion; SENSITIZED SOLAR-CELLS; ELECTRON-TRANSPORT; CDS; PHOTOLUMINESCENCE; NANOSTRUCTURES; LUMINESCENCE; PARTICULATE; EFFICIENCY; PARTICLES; IMPEDANCE;
D O I
10.1007/s11051-011-0517-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this article, we have decorated multiwalled carbon nanotubes (MWCNTs) scaffold with ZnO quantum dots (QDs, size in the range of 2.9-4.5 nm) and investigated their prospects for photovoltaic applications. ZnO QDs, in the present study, work as photosensitizer instead of electron transporting media as used in recent conventional strategic solar cells. ZnO QDs/MWCNTs composite shows an increased visible absorbance and quenching of the broad visible emission at around similar to 560 nm, while only ZnO QDs exhibit a strong visible emission. An efficient electron-hole separation facilitates an increase in the short-circuit current. These results show a possibility of developing a nontoxic, ZnO QDs sensitized MWCNTs composite-based photovoltaic solar cell.
引用
收藏
页码:5311 / 5319
页数:9
相关论文
共 45 条
[1]   Electronic interaction between photoexcited poly(p-phenylene vinylene) and carbon nanotubes [J].
Ago, H ;
Shaffer, MSP ;
Ginger, DS ;
Windle, AH ;
Friend, RH .
PHYSICAL REVIEW B, 2000, 61 (03) :2286-2290
[2]  
[Anonymous], 361451 JOINT COMM PO
[3]   Photosensitization of TiO2 Nanostructures with CdS Quantum Dots: Particulate versus Tubular Support Architectures [J].
Baker, David R. ;
Kamat, Prashant V. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (05) :805-811
[4]   Quantum Dot Sensitized Solar Cells. A Tale of Two Semiconductor Nanocrystals: CdSe and CdTe [J].
Bang, Jin Ho ;
Kamat, Prashant V. .
ACS NANO, 2009, 3 (06) :1467-1476
[5]   Theory of the impedance of charge transfer via surface states in dye-sensitized solar cells [J].
Bisquert, Juan .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2010, 646 (1-2) :43-51
[6]   Single-walled carbon nanotube scaffolds for dye-sensitized solar cells [J].
Brown, Patrick ;
Takechi, Kensuke ;
Kamat, Prashant V. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (12) :4776-4782
[7]   Comparison of the performances of dye-sensitized solar cells based on different TiO2 electrode nanostructures [J].
Bwana, Nicholas N. .
JOURNAL OF NANOPARTICLE RESEARCH, 2009, 11 (08) :1917-1923
[8]   Reduced charge recombination in a co-sensitized quantum dot solar cell with two different sizes of CdSe quantum dot [J].
Chen, J. ;
Lei, W. ;
Deng, W. Q. .
NANOSCALE, 2011, 3 (02) :674-677
[9]   Stepwise Cosensitization of Nanocrystalline TiO2 Films Utilizing Al2O3 Layers in Dye-Sensitized Solar Cells [J].
Choi, Hyunbong ;
Kim, Sanghoon ;
Kang, Sang Ook ;
Ko, Jaejung ;
Kang, Moon-Sung ;
Clifford, John N. ;
Forneli, Amparo ;
Palomares, Emilio ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (43) :8259-8263
[10]   Multistep electron transfer processes on dye co-sensitized nanocrystalline TiO2 films [J].
Clifford, JN ;
Palomares, E ;
Nazeeruddin, K ;
Thampi, R ;
Grätzel, M ;
Durrant, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (18) :5670-5671