Excess molar volumes of binary mixtures of acetonitrile with n-alkanols at 25°C

被引：17
|
作者：
Aznarez, SB [1 ]
Postigo, MA [1 ]
机构：
[1] Univ Nacl Comahue, Fac Ingn, Dept Quim, Catedra Fisicoquim, RA-1400 Buenos Aires, Neuquen, Argentina
来源：
JOURNAL OF SOLUTION CHEMISTRY | 1998年 / 27卷 / 11期
关键词：
excess molar volumes; acetonitrile + n-alkanol mixtures;
D O I：
10.1023/A:1022656505917
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Molar excess volumes of acetonitrile with ten n-alkanols (from methanol to decanol) were determined from density measurements at 25 degrees C and normal atmospheric pressure, using a vibrating-tube densimeter. V-E for acetonitrile + methanol mixtures are negative over the entire range of mole fractions. The ethanol and propanol mixtures exhibit sigmoidal curves and positive values are obtained for all remaining mixtures. The results for V-E were compared with those obtained using several theoretical models.
引用
收藏
页码：1045 / 1053
页数：9
相关论文
共 50 条
  • [41] EXCESS MOLAR VOLUMES OF BINARY-MIXTURES OF DIOLS AND WATER
    CZECHOWSKI, G
    ZYWUCKI, B
    JADZYN, J
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (01): : 55 - 57
  • [42] Excess molar volumes and viscosities of binary mixtures of epichlorohydrine and alcohols
    Vural, US
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2005, 79 (07): : 1096 - 1101
  • [43] Topological investigations in binary mixtures containing ether: Molar excess volumes and molar excess enthalpies
    Sharma, VK
    Rajni
    Romi
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2001, 40 (12): : 1277 - 1281
  • [44] MOLAR EXCESS VOLUMES OF ACETONITRILE + CHLOROFORM AND OF ACETONITRILE + DEUTEROCHLOROFORM
    HANDA, YP
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (02): : 117 - 120
  • [45] Excess molar volume of binary mixtures of dehydrolinalool plus alkanols at 308.15 K
    Wang, CM
    Li, HR
    Zhu, LH
    Han, SJ
    FLUID PHASE EQUILIBRIA, 2001, 189 (1-2) : 129 - 133
  • [46] Excess molar volume of binary mixtures of methylheptenone plus alkanols at 298.15 K
    Xiao, X
    Li, HR
    Wang, CM
    Wang, Q
    Han, SJ
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2002, 18 (04) : 427 - 429
  • [47] Investigations on the Thermophysical Properties of the Binary Mixtures of Ethyl Laurate with Four n-Alkanols
    Dan Li
    Meng Guo
    Qian Wu
    Menglei Li
    Nannan Ruan
    Lijun Gao
    Journal of Solution Chemistry, 2020, 49 : 1237 - 1249
  • [48] Excess Molar Volume of Binary Mixtures of Methylheptenone+Alkanols at 298.15 K
    XIAO Xi
    Chemical Research in Chinese Universities, 2002, (04) : 427 - 429
  • [49] Thermodynamic properties of binary mixtures of cyclohexanone with n-alkanols (C1-C5) at 293.15 K
    Tsierkezos, NG
    Molinou, IE
    Filippou, AC
    JOURNAL OF SOLUTION CHEMISTRY, 2005, 34 (12) : 1371 - 1386
  • [50] Solubility of n-alkanols (C16, C18, C20) in binary solvent mixtures
    Domanska, Urszula
    Fluid Phase Equilibria, 1992, v (02) : 223 - 248
12345