The Effect of Manganese Substituted M-type Hexagonal Ba-ferrite

被引:14
作者
Lee, In Kyu [1 ]
Sur, Jung Chul [2 ]
Shim, In-Bo [1 ]
Kim, Chul Sung [1 ]
机构
[1] Kookmin Univ, Dept Phys, Seoul 136702, South Korea
[2] Wonkwang Univ, Dept Microelect & Display Technol, Iksan 570749, South Korea
关键词
Ba-ferrite; Mossbauer spectra; magnetocrystalline anisotropy; cation distribution; MAGNETIC-PROPERTIES; SITE PREFERENCE; BARIUM FERRITE; CO-TI; PARTICLES; FILMS;
D O I
10.4283/JMAG.2009.14.2.093
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Mn-substituted M-type Ba-ferrite (BaFe(12-x)Mn(x)O(19); x = 0, 2, 4, 6) powders were prepared by the HTTD (High Temperature Thermal Decomposition) method. The effect of Mn(3+) Jahn-Teller ions on the magnetic properties has been studied by x-ray diffraction, vibrating sample magnetometry, and Mossbauer spectroscopy. With increasing Mn substitution, the lattice parameter a(0) increases while c(0) decreases. The magnetocrystalline anisotropy constants (K(1)) were determined as 2.9, 2.2, 1.8, and, 1.3 x 10(6) erg/cm(3) for x = 0, 2, 4, and 6, respectively, by the LAS method. We have studied the change of cation distribution by Mossbauer spectroscopy which is closely related to K(1).
引用
收藏
页码:93 / 96
页数:4
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