Choline chloride and tartaric acid, a Natural Deep Eutectic Solvent for the efficient extraction of phenolic and carotenoid compounds

被引：127

作者：

Koutsoukos, Spyridon ^{[1
]}

Tsiaka, Thalia ^{[2
]}

Tzani, Andromachi ^{[1
]}

Zoumpoulakis, Panagiotis ^{[2
]}

Detsi, Anastasia ^{[1
]}

机构：

[1] Natl Tech Univ Athens, Sch Chem Engn, Dept Chem Sci, Lab Organ Chem, Zografos, Greece

[2] Natl Hellen Res Fdn, Inst Biol Med Chem & Biotechnol, Lab Mol Anal, Athens, Greece

来源：

JOURNAL OF CLEANER PRODUCTION | 2019年 / 241卷

关键词：

Natural Deep Eutectic Solvent; Extraction; Phenolics; Carotenoids; High energy techniques; IONIC LIQUIDS; ANTIOXIDANT; PROPOLIS; MEDIA; CONSTITUENTS;

D O I：

10.1016/j.jclepro.2019.118384

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Green extraction processes to obtain high value bioactive compounds from raw natural materials and wastes has gained attention the past few years. In the present study, we investigated a Natural Deep Eutectic Solvent derived from two natural products, namely choline chloride and L(+)-tartaric acid as a potential solvent for the extraction of phenolic compounds from Greek propolis and carotenoids from apricot and shrimp wastes. High energy techniques were used in combination with the NaDES in order to minimize the extraction time and maximize the yield. Two- and three-level experimental design was implemented in order to statistically investigate the correlation between the extraction conditions and the obtained extracts and find the optimum conditions. The proposed methodology resulted in the efficient extraction of the desired bioactive compounds despite their different structure and polarity. The optimized process could be considered as a competitive alternative to conventional processes. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页数：11

共 42 条

[1] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[2]

Alanon M., 2018, ARAB J CHEM

[3] On the properties of (choline chloride plus lactic acid) deep eutectic solvent with methanol mixtures [J].

Alcalde, Rafael ;

Atilhan, Mert ;

Aparicio, Santiago .

JOURNAL OF MOLECULAR LIQUIDS, 2018, 272 :815-820

[4]

Aryee A.N., 2018, CURR OPIN FOOD SCI

[5] Recent progress in pharmacological research of propolis [J].

Banskota, AH ;

Tezuka, Y ;

Kadota, S .

PHYTOTHERAPY RESEARCH, 2001, 15 (07) :561-571

[6]

BRAND-WILLIAMS W, 1995, FOOD SCI TECHNOL-LEB, V28, P25

[7]

Brereton R.G., 2003, DATA ANAL LAB CHEM P, DOI DOI 10.1002/0470863242

[8] Cholinium-based deep eutectic solvents and ionic liquids for lipase-catalyzed synthesis of butyl acetate [J].

Bubalo, Marina Cvjetko ;

Tusek, Ana Jurinjak ;

Vinkovic, Marijana ;

Radosevic, Kristina ;

Srcek, Visnja Gaurina ;

Redovnikovic, Ivana Radojcic .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2015, 122 :188-198

[9] Phenolic and carotenoid composition of canned peaches (Prunus persica) and apricots (Prunus armeniaca) as affected by variety and peeling [J].

Campbell, Oluranti E. ;

Padilla-Zakour, Olga I. .

FOOD RESEARCH INTERNATIONAL, 2013, 54 (01) :448-455

[10] Propolis, an old remedy used in modem medicine [J].

Castaldo, S ;

Capasso, F .

FITOTERAPIA, 2002, 73 :S1-S6

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