The state of the field: from inception to commercialization of metal-organic frameworks

被引:80
作者
Chen, Zhijie [1 ,2 ]
Wasson, Megan C. [1 ,2 ]
Drout, Riki J. [1 ,2 ]
Robison, Lee [1 ,2 ]
Idrees, Karam B. [1 ,2 ]
Knapp, Julia G. [1 ,2 ]
Son, Florencia A. [1 ,2 ]
Zhang, Xuan [1 ,2 ]
Hierse, Wolfgang [4 ]
Kuehn, Clemens [4 ]
Marx, Stefan [5 ]
Hernandez, Benjamin [6 ]
Farha, Omar K. [1 ,2 ,3 ]
机构
[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, 2145 Sheridan Rd, Evanston, IL 60208 USA
[3] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[4] Merck KGaA, Frankfurter Str 250, D-64293 Darmstadt, Germany
[5] BASF SE, RC-OI-M300,Carl Bosch Str 38, D-67056 Ludwigshafen, Germany
[6] NuMat Technol, 8025 Lamon Ave, Skokie, IL 60077 USA
基金
美国国家科学基金会;
关键词
HIGH METHANE STORAGE; ASSISTED LINKER EXCHANGE; INFINITE POLYMERIC FRAMEWORKS; POSTSYNTHETIC LIGAND-EXCHANGE; SECONDARY BUILDING UNITS; CARBON-DIOXIDE CAPTURE; ULTRAHIGH SURFACE-AREA; DE-NOVO SYNTHESIS; RETICULAR CHEMISTRY; HYDROGEN STORAGE;
D O I
10.1039/d0fd00103a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
As chemists and materials scientists, it is our duty to synthesize and utilize materials for a multitude of applications that promote the development of society and the well-being of its citizens. Since the inception of metal-organic frameworks (MOFs), researchers have proposed a variety of design strategies to rationally synthesize new MOF materials, studied their porosity and gas sorption performances, and integrated MOFs onto supports and into devices. Efforts have explored the relevance of MOFs for applications including, but not limited to, heterogeneous catalysis, guest delivery, water capture, destruction of nerve agents, gas storage, and separation. Recently, several start-up companies have undertaken MOF commercialization within industrial sectors. Herein, we provide a brief overview of the state of the MOF field from their design and synthesis to their potential applications, and finally, to their commercialization.
引用
收藏
页码:9 / 69
页数:61
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