Dielectric relaxation and structural studies of binary mixture of benzonitrile and o-nitrophenol in benzene at different temperatures

被引：7

作者：

Kasthury, K. ^{[1
]}

Mayilavelan, S. ^{[1
]}

Balakrishnan, R. ^{[1
]}

机构：

[1] Kanchi Mamunivar Ctr Post Grad Studies, Dept Phys, Pondicherry 605008, India

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2006年 / 129卷 / 03期

关键词：

relaxation time; dielectric relaxation time; dielectric constant; dielectric loss;

D O I：

10.1016/j.molliq.2005.11.039

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A study has been made on the interaction of binary mixtures of benzonittile and o-nitrophenol in benzene by an experimental approach at microwave frequency (9.985 GHz) at different temperatures. From the measured dielectric data, the relaxation times, the dipole moments, thermodynamical parameters, such as free energy, enthalpy and entropy have been computed. Comparison has been established with that of the corresponding energy parameters from viscous flow studies. The dielectric relaxation process like viscous flow can be treated as rate processes. Solute-solvent and solute-solute type of molecular association have been established. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：125 / 128

页数：4

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