Application of 1-Allyl-3-(1-butyl)imidazolium Chloride in the Synthesis of Cellulose Esters: Properties of the Ionic Liquid, and Comparison with Other Solvents

被引：30

作者：

Fidale, Ludmila C. ^{[1
]}

Possidonio, Shirley ^{[1
]}

El Seoud, Omar A. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Chem, BR-05513970 Sao Paulo, Brazil

来源：

MACROMOLECULAR BIOSCIENCE | 2009年 / 9卷 / 08期

基金：

巴西圣保罗研究基金会;

关键词：

activation energy adsorption; cellulose acetate; cellulose butyrate; ionic Liquids (ILs); 1-allyl-3-(1-butyl)imidazolium chloride (AlBuImCl); DILUTE-SOLUTION PROPERTIES; RHEOLOGICAL PROPERTIES; BACTERIAL CELLULOSE; DISSOLUTION; DERIVATIVES; ACYLATION; ACETATE; POLYSACCHARIDES; SOLVATION; CHEMISTRY;

D O I：

10.1002/mabi.200900034

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The ionic liquid (IL), 1-allyl-3-(1-butyl)imidazolium chloride (AlBuImCl), has been synthesized and its properties determined. Increase in the temperature increased its conductivity and decreased its density, polarity, and viscosity. Microcrystalline cellulose (MCC), dissolves in thisIL by heating at 80 degrees C; this did not affect its degree of polymerization, decreased its index of crystallinity (Ic), and changed in morphology after regeneration. Convenient acylation of MCC was achieved by using 50% excess anhydride at 80 degrees C, for 24 or 48 h for acetic and butyric anhydride, respectively. The composition of the mixed esters depended on the initial ratio of the anhydrides, and their order of addition.

引用

页码：813 / 821

页数：9

共 50 条

[1] Synthesis and Characterization of Cellulose Tosylate in an Ionic Liquid 1-Butyl-3-Methylimidazolium Chloride
Liu, Yang
Peng, Hong
Liu, Shijie
Peng, Wenyi
JOURNAL OF BIOBASED MATERIALS AND BIOENERGY, 2016, 10 (01) : 18 - 26
[2] Synthesis and properties of 1-allyl-3-methyl-imidazolium bicarbonate room temperature ionic liquid
Xu, H.
Liao, J.
Li, Q.
You, L.
Kang, S.
Chen, H.
He, B.
Tang, Q.
MATERIALS RESEARCH INNOVATIONS, 2014, 18 (06) : 457 - 460
[3] Gold microcrystal synthesis via reduction of HAuCl4 by cellulose in the ionic liquid 1-butyl-3-methyl imidazolium chloride
Li, Zhonghao
Friedrich, Alwin
Taubert, Andreas
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (09) : 1008 - 1014
[4] Homogeneous synthesis of cellulose fatty esters in ionic liquid (1-butyl-3-methylimidazolium chloride) and study of their comparative antifriction property
Singh, Raj K.
Gupta, Piyush
Sharma, Om P.
Ray, Siddharth S.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 24 : 14 - 19
[5] Dissolution performance of coals in ionic liquid 1-butyl-3-methyl-imidazolium chloride
Lei, Zhi-Ping
Cheng, Lu-Lu
Zhang, Su-Fang
Zhang, Yan-Qiu
Shui, Heng-Fu
Ren, Shi-Biao
Wang, Zhi-Cai
FUEL PROCESSING TECHNOLOGY, 2015, 129 : 222 - 226
[6] Reductive Splitting of Cellulose in the Ionic Liquid 1-Butyl-3-Methylimidazolium Chloride
Ignatyev, Igor A.
Van Doorslaer, Charlie
Mertens, Pascal G. N.
Binnemans, Koen
De Vos, Dirk E.
CHEMSUSCHEM, 2010, 3 (01) : 91 - 96
[7] Solvation properties of 1-butyl 2, 3-dimethyl imidazolium chloride ionic liquid in aqueous and aqueous glycine solutions at different temperatures using volumetric and compressibility parameters
Jain, Anuja
Zodape, Sangesh P.
JOURNAL OF MOLECULAR LIQUIDS, 2022, 363
[8] Cellulose conversion into alkylglycosides in the ionic liquid 1-butyl-3-methylimidazolium chloride
Ignatyev, Igor A.
Mertens, Pascal G. N.
Van Doorslaer, Charlie
Binnemans, Koen
de Vos, Dirk E.
GREEN CHEMISTRY, 2010, 12 (10) : 1790 - 1795
[9] Synthesis and characterization of 1-butyl 3-methyl imidazolium phosphomolybdate molecular salt
Rao, G. Ranga
Rajkumar, T.
Varghese, Babu
SOLID STATE SCIENCES, 2009, 11 (01) : 36 - 42
[10] Effect of Oil on Cellulose Dissolution in the Ionic Liquid 1-Butyl-3-methyl Imidazolium Acetate
Lefroy, Katherine S.
Murray, Brent S.
Ries, Michael E.
ACS OMEGA, 2022, : 37532 - 37545

← 1 2 3 4 5 →