Fe-Catalyzed Cross-Dehydrogenative Coupling Reactions

被引：77
|
作者：
Lv, Leiyang [1 ]
Li, Zhiping [1 ]
机构：
[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
来源：
TOPICS IN CURRENT CHEMISTRY | 2016年 / 374卷 / 04期
基金：
美国国家科学基金会;
关键词：
Cross-dehydrogenative coupling (CDC); Iron catalysis; C-H bond; C-C bond; C-X bond; C-H BOND; EFFICIENT COPPER CATALYST; OXIDATIVE ACTIVATION; N-ALKYLATION; 1,3-DICARBONYL COMPOUNDS; TERTIARY-AMINES; ARYLATION CDA; IRON; FUNCTIONALIZATION; ARENES;
D O I：
10.1007/s41061-016-0038-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cross-dehydrogenative coupling (CDC), which enables the formation of carbon-carbon (C-C) and C-heteroatom bonds from the direct coupling of two C-H bonds or C-H/X-H bonds, represents a new state of the art in the field of organic chemistry. Iron, a prominent metal, has already shown its versatile application in chemical synthesis. This review attempts to provide a comprehensive understanding of the evolution of cross-dehydrogenative coupling via iron catalysis, as well as its application in synthetic chemistry.
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页数：39
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