Fe-Catalyzed Cross-Dehydrogenative Coupling Reactions

被引：77

作者：

Lv, Leiyang ^{[1
]}

Li, Zhiping ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

TOPICS IN CURRENT CHEMISTRY | 2016年 / 374卷 / 04期

基金：

美国国家科学基金会;

关键词：

Cross-dehydrogenative coupling (CDC); Iron catalysis; C-H bond; C-C bond; C-X bond; C-H BOND; EFFICIENT COPPER CATALYST; OXIDATIVE ACTIVATION; N-ALKYLATION; 1,3-DICARBONYL COMPOUNDS; TERTIARY-AMINES; ARYLATION CDA; IRON; FUNCTIONALIZATION; ARENES;

D O I：

10.1007/s41061-016-0038-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cross-dehydrogenative coupling (CDC), which enables the formation of carbon-carbon (C-C) and C-heteroatom bonds from the direct coupling of two C-H bonds or C-H/X-H bonds, represents a new state of the art in the field of organic chemistry. Iron, a prominent metal, has already shown its versatile application in chemical synthesis. This review attempts to provide a comprehensive understanding of the evolution of cross-dehydrogenative coupling via iron catalysis, as well as its application in synthetic chemistry.

引用

页数：39

共 107 条

[1] C-N bond forming cross-coupling reactions: an overview [J].

Bariwal, Jitender ;

Van der Eycken, Erik .

CHEMICAL SOCIETY REVIEWS, 2013, 42 (24) :9283-9303

[2] Iron-Catalyzed Oxidative Direct α-C-H Bond Functionalization of Cyclic Ethers: Selective C-O Bond Formation in the Presence of a Labile Aldehyde Group [J].

Barve, Balaji D. ;

Wu, Yang-Chang ;

El-Shazly, Mohamed ;

Korinek, Michal ;

Cheng, Yuan-Bin ;

Wang, Jeh-Jeng ;

Chang, Fang-Rong .

ORGANIC LETTERS, 2014, 16 (07) :1912-1915

[3] Iron Catalysis in Organic Synthesis [J].

Bauer, Ingmar ;

Knoelker, Hans-Joachim .

CHEMICAL REVIEWS, 2015, 115 (09) :3170-3387

[4] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[5] Iron-Catalyzed Regioselective Direct Oxidative Aryl-Aryl Cross-Coupling [J].

Chandrasekharam, Malapaka ;

Chiranjeevi, Barreddi ;

Gupta, Kankatala S. V. ;

Sridhar, B. .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (24) :10229-10235

[6] Iron-Catalyzed Direct C(sp3)-H Amination Reactions of Isochroman Derivatives with Primary Arylamines under Mild Conditions [J].

Chen, Di ;

Pan, Fuyou ;

Gao, Jianrong ;

Yang, Jianguo .

SYNLETT, 2013, 24 (16) :2085-2088

[7] Palladium(II)-Catalyzed C-H Activation/C-C Cross-Coupling Reactions: Versatility and Practicality [J].

Chen, Xiao ;

Engle, Keary M. ;

Wang, Dong-Hui ;

Yu, Jin-Quan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (28) :5094-5115

[8] Iron-Catalyzed Hetero-Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines [J].

Cheng, Ying ;

Dong, Wanrong ;

Wang, Long ;

Parthasarathy, Kanniyappan ;

Bolm, Carsten .

ORGANIC LETTERS, 2014, 16 (07) :2000-2002

[9] Iron-catalyzed aryl-aryl cross coupling route for the synthesis of 1-(2-amino)-phenyl)dibenzo[b,d]furan-2-ol derivatives and their biological evaluation [J].

Chiranjeevi, Barreddi ;

Koyyada, Ganesh ;

Prabusreenivasan, S. ;

Kumar, Vanaja ;

Sujitha, Pombala ;

Kumar, C. Ganesh ;

Sridhar, B. ;

Shaik, Saida ;

Chandrasekharam, Malapaka .

RSC ADVANCES, 2013, 3 (37) :16475-16485

[10] Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes [J].

Correa, Arkaitz ;

Mancheno, Olga Garcia ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (06) :1108-1117

← 1 2 3 4 5 6 7 8 9 10 →