Application of titanium phosphate prepared from acidic titanium dioxide wastewater to remove cerium (III) in aqueous solution

被引:13
作者
Liu, Zhaowang [1 ,2 ]
Feng, Yali [1 ]
Li, Haoran [2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Civil & Resources Engn, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
关键词
acidic wastewater; titanium phosphate; cerium (III); adsorption mechanism; kinetics; RARE-EARTH-ELEMENTS; ADSORPTION-ISOTHERM; RECOVERY; EXTRACTION; KINETICS; SORPTION; IONS; EQUILIBRIUM; LEAD;
D O I
10.1016/j.colsurfa.2021.127613
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Titanium phosphate was prepared from acidic titanium dioxide wastewater, and its adsorption behavior for cerium (III) was studied. The experimental results of XRD, XRF, SEM, EDS, BET, FT-IR showed that the prepared titanium phosphate had an amorphous structure and excellent specific surface area. The adsorption process of cerium was in accordance with Langmuir isotherm model and Pseudo-first-order kinetic model. When the temperature was 298 K, the maximum adsorption capacity reached 158 mg/g. At the same time, the adsorption process was spontaneous, endothermic and selective. Coordination was the main cause of adsorption, electrostatic adsorption and intraparticle diffusion also played a role. Titanium phosphate was a promising adsorbent with good adsorption stability and reusability.
引用
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页数:10
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