Co-crystallization of oxadiazole-bridged pyridyl-N-oxide building modules with R-aromatics (R = -OH, -NH2 and -COOH)

被引:32
作者
Hou, Gui-Ge [1 ]
Ma, Jian-Ping [1 ]
Wang, Le [1 ]
Wang, Ping [1 ]
Dong, Yu-Bin [1 ]
Huang, Ru-Qi [1 ]
机构
[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Engn Res Ctr Pesticide & Med Intermediate Clean P, Key Lab Mol & Nano Probe,Minist Educ, Jinan 250014, Peoples R China
来源
CRYSTENGCOMM | 2010年 / 12卷 / 12期
关键词
TUNABLE LUMINESCENT PROPERTIES; ORGANIC ROTAXANE FRAMEWORKS; BENZOIC-ACID DERIVATIVES; COORDINATION POLYMERS; HYDROGEN-BOND; TRIMESIC ACID; CRYSTALS; COMPLEXES; 3D; DESIGN;
D O I
10.1039/b923810g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of oxadiazole bridging pyridyl-N-oxides (2,5-bis(4-pyridyl-N-oxide)-1,3,4-oxadiazole (A1) and 2-(4-pyridyl)-5-(4-pyridyl-N-oxide)-1,3,4-oxadiazole (A2)) with different substituted aromatics (R-aromatics, R = -OH, -NH2, -COOH) have been investigated. Eight new organic co-crystals of 1-8 were synthesized and characterized by elemental analysis, FTIR spectroscopy, H-1 NMR and single-crystal X-ray diffraction. The results display the distinct substituent effect on the hydrogen-bonded self-assembly systems. In addition, the luminescent properties of A1-A2 and 1-8 were investigated in the solid state.
引用
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页码:4287 / 4303
页数:17
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