A new charging mode of Li-ion batteries with LiFePO4/C composites under low temperature

被引:59
作者
Zhao, Xiao Wei [1 ]
Zhang, Guo Yu [1 ]
Yang, Lin [1 ]
Qiang, Jia Xi [1 ]
Chen, Zi Qiang [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Mech Engn, Shanghai 200030, Peoples R China
关键词
Charging mode; Li-ion battery; LiFePO4; Low temperature; THERMAL-BEHAVIOR; LITHIUM; PERFORMANCE; ELECTROLYTES; CARBONATE;
D O I
10.1007/s10973-010-1038-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
Li-ion batteries with LiFePO4/C composites are difficult to be charged at low temperatures. In order to improve the low temperature performance of LiFePO4/C power batteries, the charge-discharge characteristics were studied at different temperatures, and a new charging mode under low temperature was proposed. In the new charging mode, the batteries were excited by current pulses with the charge rates between 0.75 C and 2 C, while the discharge rates between 3 and 4 C before the conventional charging (CC-CV). Results showed that the surface temperature of Li-ion battery ascended to 3 A degrees C at the end of pulse cycling when the environment temperature was -10 A degrees C. Comparing with the conventional charging, the whole charge time was cut by 36 min (23.4%) and the capacity was 7.1% more at the same discharge rate, respectively.
引用
收藏
页码:561 / 567
页数:7
相关论文
共 16 条
[1]   Studies on glass transition of lithium-iron phosphate glasses [J].
Gorzkowska, I. ;
Jozwiak, P. ;
Garbarczyk, J. E. ;
Wasiucionek, M. ;
Julien, C. M. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 93 (03) :759-762
[2]   New Li-ion electrolytes for low temperature applications [J].
Herreyre, S ;
Huchet, O ;
Barusseau, S ;
Perton, F ;
Bodet, JM ;
Biensan, P .
JOURNAL OF POWER SOURCES, 2001, 97-8 :576-580
[3]   High-rate properties of LiFePO4/carbon composites as cathode materials for lithium-ion batteries [J].
Kuwahara, Akira ;
Suzuki, Shinya ;
Miyayama, Masaru .
CERAMICS INTERNATIONAL, 2008, 34 (04) :863-866
[4]   A low-temperature electrolyte for lithium and lithium-ion batteries [J].
Plichta, EJ ;
Behl, WK .
JOURNAL OF POWER SOURCES, 2000, 88 (02) :192-196
[5]   Development of low temperature Li-ion electrolytes for NASA and DoD applications [J].
Plichta, EJ ;
Hendrickson, M ;
Thompson, R ;
Au, G ;
Behl, WK ;
Smart, MC ;
Ratnakumar, BV ;
Surampudi, S .
JOURNAL OF POWER SOURCES, 2001, 94 (02) :160-162
[6]   Thermal behaviors of lithium-ion batteries during high-rate pulse cycling [J].
Saito, Y .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :770-774
[7]   Thermal behavior analysis of lithium-ion batteries for electric and hybrid vehicles [J].
Sato, N .
JOURNAL OF POWER SOURCES, 2001, 99 (1-2) :70-77
[8]   Improved low-temperature performance of lithium-ion cells with quaternary carbonate-based electrolytes [J].
Smart, MC ;
Ratnakumar, BV ;
Whitcanack, LD ;
Chin, KB ;
Surampudi, S ;
Croft, H ;
Tice, D ;
Staniewicz, R .
JOURNAL OF POWER SOURCES, 2003, 119 :349-358
[9]   Effect of entropy change of lithium intercalation in cathodes and anodes on Li-ion battery thermal management [J].
Viswanathan, Vilayanur V. ;
Choi, Daiwon ;
Wang, Donghai ;
Xu, Wu ;
Towne, Silas ;
Williford, Ralph E. ;
Zhang, Ji-Guang ;
Liu, Jun ;
Yang, Zhenguo .
JOURNAL OF POWER SOURCES, 2010, 195 (11) :3720-3729
[10]   Thermal behavior of nickel/metal hydride battery during charging and discharging [J].
Yang, K. ;
Li, D. H. ;
Chen, S. ;
Wu, F. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 95 (02) :455-459